Jinbao Zhao, Fan Xinhui, Bing Li, Ke‐Ke Yang, Y. Kong, Zhaofeng Wang, Jie Liu
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引用次数: 1
摘要
通过热分析试验系统研究了(Cu43Zr48Al9)100-xREx(x=0-4, RE: Y, Gd)块状金属玻璃在过冷液区的宽度、变形和粘度变化。通过对过冷液区宽度、变形和粘度的分析,得到了(Cu43Zr48Al9)100-xREx (x=0-4, RE: Y, Gd)在过冷液区的非晶态成形能力、热稳定性和热塑性成形能力。结果发现,稀土元素Y和Gd的加入改善了非晶成形能力、热稳定性、粘度和变形,而添加稀土Y、Gd、粘度与ΔT没有明显的联系。随着Y含量的增加,热稳定性先增大后减小,粘度先减小后增大后减小,变形先增大后减小,初步揭示了粘度与非晶成形能力之间的关系。(Cu43Zr48Al9)98Y2非晶合金加入少量Y后,具有较好的热稳定性和热塑性成形性。
Amorphous Forming Ability, Thermal Stability, Viscosity and Thermoplastic Formability of (Cu43Zr48Al9)100-xREx (x=0-4, RE: Y,Gd) Alloy
The width, deformation and viscosity change of super cooled liquid region of (Cu43Zr48Al9)100-xREx(x=0-4, RE: Y, Gd) bulk metallic glasses in super cooled liquid region are systemically investigated by thermoanalysis tests. By analyzing the width, deformation and viscosity of super cooled liquid region, the amorphous forming ability, thermal stability and thermoplastic forming ability of (Cu43Zr48Al9)100-xREx (x=0-4, RE: Y, Gd) in the super cooled liquid region were obtained. It was found that the addition of rare earth elements Y and Gd improved amorphous forming ability, thermal stability, viscosity and deformation, however, by adding rare earth Y, Gd, viscosity and ΔT was no obvious connection. With the increase of Y content, the thermal stability first increases and then decreases, the viscosity decreases firstly, then increases and decreases finally, the deformation increases firstly and then decreases, it preliminary reveals the relationship between viscosity and amorphous forming ability. (Cu43Zr48Al9)98Y2 amorphous alloy has better thermal stability and thermoplastic formability by adding a small amount of Y.