激光辐照对纳米多孔碳材料金属掺杂过程的影响

IF 0.9 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Solid State Pub Date : 2023-06-29 DOI:10.15330/pcss.24.2.403-409
I. Budzulyak, L. Yablon, M. Khemii, V. Kotsyubynsky, B. Rachiy, R. Ilnytskyi, R. I. Kryvulych
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引用次数: 1

摘要

研究表明,在活性炭材料中掺杂铬和锰,可使基于双电层(DEL)充放电机理的存储器件的比电容提高约70%,内阻降低30- 35%。这种上升的主要原因是由于电子态密度的增加导致电子能谱的转变,因此大量的电解质离子(主要是正离子)参与DEL的形成,并导致这些器件的比电容增加。研究表明,激光照射可刺激金属渗透到碳材料中。
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Stimulation of the metal doping process of nanoporous carbon material by laser irradiation
It has been established that the doping of activated carbon material with chromium and manganese increases the specific capacitance of storage devices based on the charge-discharge mechanism of a double electric layer (DEL) by ~70 % and leads to a decrease in their internal resistance by 30-35 %. The main reason for this rise is the transformation of the electron energy spectrum due to an increase in the density of electronic states, as a result of which a much larger number of electrolyte ions (primarily positive ones) participate in the formation of DEL and cause an increase in the specific capacitance of these devices. It has been shown that laser irradiation stimulates the metal penetration into the bulk of carbon material.
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来源期刊
CiteScore
1.70
自引率
14.30%
发文量
83
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