Mirella Romanelli Vicente Bertolo, Rafael Leme, Virginia da Conceição Amaro Martins, A. M. de Guzzi Plepis, S. Bogusz Junior
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引用次数: 5
摘要
在本研究中,研究了具有活性的农业工业残留物石榴皮提取物(PPE)对壳聚糖(C)和明胶(G)涂料的流变性能的影响。为此,研究了PPE浓度(2或4 mg PPE G−1溶液)及其加入顺序(在C或CG混合物中)与聚合物溶液的流变性能的关系。所有溶液的黏性都大于弹性(G″> G’),PPE浓度的变化对加入PPE的CG混合物(CGPPE2和CGPPE4)样品的黏性影响更大。在CG混合物中加入PPE增加了模交叉处的角频率,表明形成了更耐腐蚀的聚合物网络。在流动结果中也观察到这种趋势,PPE的加入降低了溶液的假塑性行为,因为聚合物和酚类化合物之间的交联更大。总的来说,所有研究的溶液都显示出适合提议应用的粘度,并且有可能说明在涂层制备过程中标准化组分添加顺序的重要性。
Rheological Characterization of the Influence of Pomegranate Peel Extract Addition and Concentration in Chitosan and Gelatin Coatings
In this study, the effects of an agro-industrial residue with active properties, pomegranate peel extract (PPE), were evaluated on the rheological properties of potential coatings based on chitosan (C) and gelatin (G). For this, rheological properties of the polymeric solutions were investigated in relation to PPE concentration (2 or 4 mg PPE g−1 solution), and to its incorporation order into the system (in C or in CG mixture). All solutions were more viscous than elastic (G″ > G′), and the change in PPE concentration had a greater influence accentuating the viscous character of the samples in which PPE was added to the CG mixture (CGPPE2 and CGPPE4). PPE addition to the CG mixture increased the angular frequency at the moduli crossover, indicating the formation of a more resistant polymeric network. This tendency was also observed in flow results, in which PPE addition decreased the pseudoplastic behavior of the solutions, due to a greater cross-linking between the polymers and the phenolic compounds. In general, all the studied solutions showed viscosities suitable for the proposed application, and it was possible to state the importance of standardizing the addition order of the components during the preparation of a coating.