氟化二氧化钛材料催化及光催化乙酰丙酸酯化反应研究

IF 0.9 Q3 ENGINEERING, MULTIDISCIPLINARY Revista Facultad De Ingenieria-universidad De Antioquia Pub Date : 2021-05-24 DOI:10.17533/UDEA.REDIN.20210531

Claudia Patricia Castañeda Martínez, José Jobanny Martínez Zambrano, and Camillo La Mesa

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引用次数: 1

摘要

本研究考察了溶胶-凝胶法原位改性的含氟二氧化钛材料(tio2 - f1%和tio2 - f5%)在催化和光催化乙酰丙酸酯化反应中的合成、表征和活性。通过x射线衍射、紫外-可见漫反射光谱、热分析和吡啶吸附测定了材料的理化性质。结果表明，氟阴离子的加入降低了光催化反应中乙酰丙酸的转化率;然而，在催化活化中，观察到氟材料的转化率略有提高。最后，在卤化溶剂(CCl4)存在下，光解反应有利于在1小时内转化率达到100%。

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Esterification of levulinic acid via catalytic and photocatalytic processes using fluorinated titanium dioxide materials

This study evaluated the synthesis, characterization, and activity of fluorinated titanium dioxide materials (TiO2-F 1% and TiO2-F 5%) in-situ modified by the sol-gel method in the esterification reaction of levulinic acid conducted by catalytic and photocatalytic processes. The physicochemical properties of the materials were determined by X-ray diffraction, UV–Vis diffuse reflectance spectroscopy, thermal analysis, and pyridine adsorption. It was found that the inclusion of fluoride anion causes a decrease in the levulinic acid conversion by photocatalytic reaction; however, in the catalytic activation, a slight increase in the conversion using the fluoride materials was observed. Finally, the reaction in the presence of halogenated solvents (CCl4) by photolysis reaction favors a conversion of 100% in 1h.

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来源期刊

Revista Facultad De Ingenieria-universidad De Antioquia 工程技术-工程：综合

CiteScore

2.00

自引率

0.00%

发文量

审稿时长

2 months

期刊介绍： Revista Facultad de Ingenieria started in 1984 and is a publication of the School of Engineering at the University of Antioquia. The main objective of the journal is to promote and stimulate the publishing of national and international scientific research results. The journal publishes original articles, resulting from scientific research, experimental and or simulation studies in engineering sciences, technology, and similar disciplines (Electronics, Telecommunications, Bioengineering, Biotechnology, Electrical, Computer Science, Mechanical, Chemical, Environmental, Materials, Sanitary, Civil and Industrial Engineering). In exceptional cases, the journal will publish insightful articles related to current important subjects, or revision articles representing a significant contribution to the contextualization of the state of the art in a known relevant topic. Case reports will only be published when those cases are related to studies in which the validity of a methodology is being proven for the first time, or when a significant contribution to the knowledge of an unexplored system can be proven. All published articles have undergone a peer review process, carried out by experts recognized for their knowledge and contributions to the relevant field. To adapt the Journal to international standards and to promote the visibility of the published articles; and therefore, to have a greater impact in the global academic community, after November 1st 2013, the journal will accept only manuscripts written in English for reviewing and publication. Revista Facultad de Ingeniería –redin is entirely financed by University of Antioquia Since 2015, every article accepted for publication in the journal is assigned a DOI number.