{"title":"脂肪族氟化合物的制备","authors":"A. L. Henne","doi":"10.1002/0471264180.OR002.02","DOIUrl":null,"url":null,"abstract":"Reactions of four types have been used for introducing fluorine atoms in to aliphatic molecules. These are listed below in the order of their practical importance at the present time. \n \n \n \nInteraction of organic halides or polyhalides with inorganic fluorides \n \n \n \n \nAddition of hydrogen fluoride to olefins and acetylene \n \n \n \n \nDirect fluorination of saturated compounds or additions of fluorine to unsaturated compounds \n \n \n \n \nReplacement of the hydroxyl group of alcohols. \n \n \n \n \nThese reactions are discussed in this chapter. \n \n \n \n \n \nKeywords: \n \naliphatic fluorine compounds; \nhydrogen fluoride; \nsilver; \nmercury; \npolyhalides; \nunsaturated compounds; \nfluorination; \norganic halides; \ndirect fluorination; \nmercury; \ninorganic fluorides","PeriodicalId":19539,"journal":{"name":"Organic Reactions","volume":"85 1","pages":"49-93"},"PeriodicalIF":0.0000,"publicationDate":"2011-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"The Preparation of Aliphatic Fluorine Compounds\",\"authors\":\"A. L. Henne\",\"doi\":\"10.1002/0471264180.OR002.02\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reactions of four types have been used for introducing fluorine atoms in to aliphatic molecules. These are listed below in the order of their practical importance at the present time. \\n \\n \\n \\nInteraction of organic halides or polyhalides with inorganic fluorides \\n \\n \\n \\n \\nAddition of hydrogen fluoride to olefins and acetylene \\n \\n \\n \\n \\nDirect fluorination of saturated compounds or additions of fluorine to unsaturated compounds \\n \\n \\n \\n \\nReplacement of the hydroxyl group of alcohols. \\n \\n \\n \\n \\nThese reactions are discussed in this chapter. \\n \\n \\n \\n \\n \\nKeywords: \\n \\naliphatic fluorine compounds; \\nhydrogen fluoride; \\nsilver; \\nmercury; \\npolyhalides; \\nunsaturated compounds; \\nfluorination; \\norganic halides; \\ndirect fluorination; \\nmercury; \\ninorganic fluorides\",\"PeriodicalId\":19539,\"journal\":{\"name\":\"Organic Reactions\",\"volume\":\"85 1\",\"pages\":\"49-93\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Reactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/0471264180.OR002.02\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Reactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/0471264180.OR002.02","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reactions of four types have been used for introducing fluorine atoms in to aliphatic molecules. These are listed below in the order of their practical importance at the present time.
Interaction of organic halides or polyhalides with inorganic fluorides
Addition of hydrogen fluoride to olefins and acetylene
Direct fluorination of saturated compounds or additions of fluorine to unsaturated compounds
Replacement of the hydroxyl group of alcohols.
These reactions are discussed in this chapter.
Keywords:
aliphatic fluorine compounds;
hydrogen fluoride;
silver;
mercury;
polyhalides;
unsaturated compounds;
fluorination;
organic halides;
direct fluorination;
mercury;
inorganic fluorides
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