钼酸铜锂纳米颗粒的合成及其光催化降解孔雀石绿的应用

M. Joshi, P. Kumawat, R. Ameta, S. Ameta
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引用次数: 0

摘要

本研究以钼酸铜锂(Li2CuMo2O8)为光催化剂,对不可生物降解的偶氮染料孔雀石绿进行了降解。该催化剂由Li2CO3、CuO和MoO3进行固相反应制备而成。研究了pH、孔雀石绿浓度、钼酸铜锂用量、光照强度等参数对合成效果的影响。测定了处理前后的化学需氧量(COD)、电导、pH、TDS、盐度、溶解氧等水质参数。孔雀石绿染料的光降解速率符合准一级动力学。对OH自由基作为氧化剂降解染料的机理进行了初步探讨
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Synthesis of Lithium Copper Molybdate Nanoparticles and their Application for Photocatalytic Degradation of Malachite Green
In the present investigation, degradation of a non biodegradable azo dye, malachite green has been carried out using lithium copper molybdate (Li2CuMo2O8) as a photocatalyst. This catalyst was prepared by solid state reaction between Li2CO3, CuO and MoO3. The effect of various parameters such as pH, concentration of malachite green, amount of lithium copper molybdate and light intensity has also been studied. Water quality parameters like chemical oxygen demand (COD), conductance, pH, TDS, salinity and dissolved oxygen have been determined before and after treatment. The rate of photodegradation of malachite green dye followed pseudofirst order kinetics. A tentative mechanism involving OH radicals as an oxidant for degradation of dye has
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