近中性环境下阴极极化条件下H70钢焊接接头应力腐蚀开裂研究

L. Nyrkova, P. Lisovyi, Larysa Gonchasrenko, S. Osadchuk, Yulia Kharchenko, Anatoly Klymenko, V. Kostin
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引用次数: 0

摘要

对X70钢焊接接头在近中性溶液NS4中阴极极化应力腐蚀开裂进行了研究。通过KS系数估计,X70钢母材的应力腐蚀开裂倾向由1.07增加到1.13,极化电位由腐蚀电位变为最大保护电位-1.05 V。这种规律与氢在X70钢中的穿透量增加有关,在最大保护电位-1.05 V时,氢在X70钢中的穿透量为0.000518 mol/m3。焊接接头的磁化率低于母材,KS系数在1.0附近变化不大。从-0,75 v到-1.05V,随着极化电位的增加,X70钢断口表面的孔洞尺寸减小,出现平面区域,从而发生断裂。在焊接接头中观察到类似的破裂性质,但视觉上可以注意到更大比例的平坦区域。确定焊接接头的断裂发生在母材上,提出在高质量焊接的前提下,合理使用应力腐蚀开裂敏感性系数KS来估计焊接接头的应力腐蚀开裂。X70钢焊接接头应力腐蚀开裂结果与主要燃气管道应力腐蚀开裂经验吻合较好,应力腐蚀裂纹沿燃气管道母材形成并发展。
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Investigation of stress-corrosion cracking of welded joint of H70 steel under cathodic polarization in near neutral environment
Study of stress-corrosion cracking of welded joints made of X70 steel at cathodic polarization in near neutral solution NS4 was carried out. It was established that the tendency of base metal of X70 steel to stress-corrosion cracking, estimated by KS coefficient, increases from 1.07 to 1.13 whereas polarization potential changing from the corrosion potential to maximum protective potential -1.05 V. Such regularity correlates with increasing of hydrogen penetration through X70 steel, which at maximum protective potential -1.05 V is equal to 0.000518 mol/m3 . Susceptibility of welded joint is lower than the base metal, KS coefficient change not much near the value 1.0. With increasing of polarization potential from -0,75V to -1.05V fracture surface of X70 steel characterized by decreasing in the size of holes and the appearance of flat areas, through that the rupture occurred. A similar nature of the rupture was observed for the welded joint, but visually larger proportion of flat areas can be noted. It was established that the rupture of the welded joint occurs on the base metal, which allows to propose stress-corrosion cracking susceptibility factor KS to be legitimately used for estimation to stress-corrosion cracking of welded joint, provided the weld is performed in a high-quality manner. Stress-corrosion cracking results of welded joint of X70 steel correlate satisfactorily with the experience of stress-corrosion cracking on main gas pipelines, where stress-corrosion cracks form and develop along the base metal of gas pipelines.
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来源期刊
Zastita materijala
Zastita materijala Materials Science-General Materials Science
CiteScore
0.80
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0.00%
发文量
26
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