{"title":"亚伯拉罕模型溶质描述符两个额外的α-氨基酸:d -色氨酸和l -酪氨酸","authors":"Ramya Motati, W. Acree","doi":"10.1080/00319104.2023.2248345","DOIUrl":null,"url":null,"abstract":"ABSTRACT Abraham model solute descriptors have been determined for the zwitterionic forms of D-tryptophan and L-tyrosine based on published mole fraction solubility data. The calculated solute descriptors describe the observed solubility data to within standard errors of 0.122 log units (or less). Treatment of each amino acid as a non-zwitterionic molecular compound led to significantly larger standard errors than were observed for the zwitterion form.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Abraham model solute descriptors for two additional α-amino acids: D-Tryptophan and L-Tyrosine\",\"authors\":\"Ramya Motati, W. Acree\",\"doi\":\"10.1080/00319104.2023.2248345\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Abraham model solute descriptors have been determined for the zwitterionic forms of D-tryptophan and L-tyrosine based on published mole fraction solubility data. The calculated solute descriptors describe the observed solubility data to within standard errors of 0.122 log units (or less). Treatment of each amino acid as a non-zwitterionic molecular compound led to significantly larger standard errors than were observed for the zwitterion form.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-08-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/00319104.2023.2248345\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/00319104.2023.2248345","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Abraham model solute descriptors for two additional α-amino acids: D-Tryptophan and L-Tyrosine
ABSTRACT Abraham model solute descriptors have been determined for the zwitterionic forms of D-tryptophan and L-tyrosine based on published mole fraction solubility data. The calculated solute descriptors describe the observed solubility data to within standard errors of 0.122 log units (or less). Treatment of each amino acid as a non-zwitterionic molecular compound led to significantly larger standard errors than were observed for the zwitterion form.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.