锰(II)配合物在碳糊电极上的电化学行为和伏安测定

Sophia Karastogianni, S. Girousi
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引用次数: 7

摘要

循环伏安法研究电化学行为及吸附溶出差分脉冲伏安法检测[Mn2+(噻吩-2-羧酸)2(三乙醇胺)]。采用循环脉冲伏安法和差分脉冲伏安法研究了锰(II)配合物[Mn2+(噻吩-2-羧酸)2(三乙醇胺)](a)在pH为4.6的醋酸缓冲液中和碳膏电极上的电化学行为。进一步提出了氧化还原机理。同时,建立了吸附溶出差分脉冲伏安法测定锰(II)配合物的方法。
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Electrochemical Behavior and Voltammetric Determination of a Manganese(II) Complex at a Carbon Paste Electrode
Investigation of the electrochemical behavior using cyclic voltammetry and detection of [Mn2+(thiophenyl-2-carboxylic acid)2 (triethanolamine)] with adsorptive stripping differential pulse voltammetry. The electrochemical behavior of a manganese(II) complex [Mn2+(thiophenyl-2-carboxylic acid)2(triethanolamine)] (A) was investigated using cyclic and differential pulse voltammetry in an acetate buffer of pH 4.6 at a carbon paste electrode. Further, an oxidation–reduction mechanism was proposed. Meanwhile, an adsorptive stripping differential pulse voltammetric method was developed for the determination of manganese(II) complex.
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