壳聚糖包裹银纳米颗粒结合聚乙烯醇净化沼气膜的制备与表征

Akshay S Kulkarni
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摘要

采用溶液法制备壳聚糖包覆银纳米粒子(cs包覆银纳米粒子)与聚乙烯醇(PVA)混合的膜。利用红外光谱、差示扫描比色法、广角x射线衍射、热重分析和扫描电镜等表征技术对制备的膜进行了形态研究和化学成分分析。系统研究了cs包覆银纳米粒子对膜膨胀的影响,以了解膜的气体分离性能。TGA结果表明,纳米银掺杂PVA膜的热稳定性提高了近两倍于平面PVA膜。此外,扫描电镜显示,cs包覆的银纳米颗粒掺入PVA膜基质中,具有良好的相容性和较高的溶胀性能。版权所有©VBRI出版社。
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Preparation and Characterization of Chitosan-Wrapped Silver Nanoparticles Incorporated Poly (Vinyl Alcohol) Membranes for Purification of Biogas
A solution technique was adopted to develop membranes in which chitosan-wrapped silver nanoparticles (CS-wrapped Ag nanoparticles) were incorporated in poly(vinyl alcohol) (PVA). The morphological studies and the chemical compositions of the prepared membranes were investigated using the characterization techniques like Infrared Spectroscopy, Differential scanning colorimetry, Wide Angle X-ray Diffraction, Thermogravimetric analysis and scanning electron microscopy. The effects of CS-wrapped Ag nanoparticles on membrane swelling were systematically studied to know the gas separation performance of the membranes. TGA showed increased thermal stability of Ag-nanoparticles incorporated PVA membranes nearly twice that of plane PVA membranes. Further, SEM revealed that CS-wrapped Ag nanoparticles incorporation into the PVA membrane matrix showed good compatibility and high swelling properties. Copyright © VBRI Press.
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