废李子石作为油源和生物柴油催化剂的利用

Marija Miladinovic, S. Pavlović, Ivana Bankovic-Ilic, Milan Kostic, Olivera S. Stamenković, V. Veljković
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引用次数: 0

摘要

探讨了利用废李子石生产生物柴油的可能性。以李子仁为原料,采用索氏提取法提取油,将整个李子石、破碎后留下的李子仁壳、榨油后留下的李子仁饼焚烧成灰。采用元素组成、孔隙度、碱强度等指标对所得灰烬进行了表征,并对酯化李子仁油的酯交换催化活性进行了测试。三种灰中不同含量的优势元素是钾、钙和镁。以李石壳灰为催化剂,考察了温度(40、50、60℃)对反应速率的影响。反应速率常数随反应温度的升高而增大,活化能达到58.8 kJ mol-1。此外,梅石壳灰经再煅烧后可作为催化剂重复利用。
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Utilization of waste plum stones as a source of oil and catalyst for biodiesel production
Possibilities of using waste plum stones in biodiesel production were investigated. The plum kernels were used as a source to obtain oil by the Soxhlet extraction method, while the whole plum stones, the plum stone shells that remained after the crashing, and the plum kernel cake that remained after the oil extraction, were burned off to obtain ashes. The collected ashes were characterized by elemental composition, porosity, and base strength and tested for catalytic activity in transesterification of esterified plum kernel oil. Dominant elements were potassium, calcium, and magnesium at different contents in the three obtained ashes. The most active catalyst was the plum stone shell ash, so the effect of temperature (40, 50, and 60?C) on the reaction rate was investigated. The reaction rate constant increased with the reaction temperature with the activation energy value of 58.8 kJ mol-1. In addition, the plum stone shell ash can be reused as a catalyst after recalcination.
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