不同碳化钨含量的高熵合金复合涂层在激光熔覆中的摩擦学特性研究

Baijiang Chen
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摘要

矿山机械恶劣的工作环境使其零部件的磨损极为严重,从而降低了其使用寿命,增加了事故发生的概率,并可能造成巨大的经济损失。因此,促进矿山机械的改进势在必行,而在易磨损设备表面熔融耐磨层是一种较为有效的改进方法。该研究通过激光熔融不同 WC 含量的 CoCrFeNiMn 高熵合金复合涂层,并通过添加剂的方法在涂层中生成第二相,实现涂层的强化。实验通过分析相的构象、结构、刚度和磨蚀性,发现所有涂层都以 FCC 相为主。当碳化钨用量超过 20 wt.% 时,涂层中会产生不同形态的 Fe3W3 (M6C) 碳化强化相。40 wt.%的涂层硬度最高,是不含 WC 颗粒涂层的 3.1 倍,30 wt.%的涂层磨蚀性最好。HT0 涂层的摩擦系数最小,为 0.27。HT600 和 HT800 的摩擦系数分别为 0.37 和 0.35。涂层的摩擦系数在室温下约 3 分钟后最为稳定,退火后的磨损阶段需要更长的时间。在磨合阶段,析出相具有支撑作用,延长了磨合期。采用所研究的方法制备的涂层可提高机械零件的耐磨性,延长其使用寿命,具有一定的经济和实用价值。
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Study on tribological properties of high entropy alloy composite coatings with different tungsten carbide contents in laser cladding

The severe working conditions of mining machinery make the wear of its parts extremely serious, thus reducing its service life, increasing the probability of accidents, and may cause huge economic wastage. So promoting the improvement of mining machinery is imperative, and the melting of wear-resistant layer on the surface of wear-prone equipment is a more effective improvement method. The study was performed by laser fusing a composite coating of CoCrFeNiMn high-entropy alloy with different WC contents, and a second phase was generated in the coating by an additive method to achieve the strengthening of the coating. The experiments revealed that all the coatings had FCC phase as the main phase by analyzing the phase conformation, structure, stiffness, and abrasiveness. When the WC dosage exceeded 20 wt.%, Fe3W3 (M6C) carbide reinforced phases with different morphologies were produced in the coatings. Forty wt.% of the coatings showed the highest hardness, which was 3.1 times better than that of the coatings without WC particles, and 30 wt.% of the coatings showed the best abrasiveness. HT0 coatings showed the least friction factor of 0.27. HT600 and HT800 corresponded to friction factors of 0.37 and 0.35, respectively. The coefficient of friction of the coating was most stable after about 3 min at room temperature, and the wear phase took longer after annealing. During the break-in phase, the precipitated phase has a supportive effect and prolongs the break-in period. The coating using the studied method improves the wear resistance of mechanical parts and extends their service life, which has some economic and practical value.

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