肯尼亚内罗毕和肯雅山地区空气和土壤中有机氯农药残留水平

J. Aucha, S. Wandiga, D. Abong’o, V. Madadi, E. M. Osoro
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摘要

本研究调查了肯尼亚内罗毕和肯尼亚山地区空气和土壤中有机氯农药残留水平。采用气相色谱-电子捕获检测器对4个站点的空气和土壤样品进行了有机氯农药(OCP)分析,并采用GC/MS进行了鉴定。目标农药为α-六氯环己烷、β-六氯环己烷、γ-六氯环己烷(林丹)、α硫丹、β硫丹和硫酸硫丹。样本是在2012年7月至2013年4月间季节性采集的。10月份空气中有机氯农药残留量为0.027±0.004 ~ 5.735±0.575 ng/ m3, 2月份为0.013±0.00 ~ 9.375±1.65 ng/ m3, 4月份为0.013±0.00 ~ 11.508±0.26ng/ m3。10月土壤有机氯农药检测浓度范围为BDL ~ 131.206±14.41ng/Kg, 2月土壤有机氯农药检测浓度范围为0.418±0.01 ~ 38.361±5.39 ng/Kg, 4月土壤有机氯农药检测浓度范围为0.406±0.007 ~ 26.877±8.89 ng/Kg。在丹多拉和工业区,被分析的持久性有机污染物在空气和土壤中的残留水平普遍较高。这表明,诸如四聚丙烯腈、一般塑料、菲利普斯工业废物和库存等工业活动是内罗毕新的持久性有机污染物的主要来源。高浓度对丹多拉居民和工业区工人的健康构成威胁。
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OrganochlorinePesticides Residue Levels in Airand Soilfrom Nairobiand Mount Kenyaregions, Kenya
Thestudy investigates the organochlorine pesticides residue level in air and soilat sites in Nairobi and Mount Kenya regions, Kenya. Air and soil samples from four sites were collected and analysed for selected organochlorine pesticides (OCP) using gas chromatography equipped with electron capture detector and confirmed using GC/MS. The targeted pesticides were α-HCH, β-HCH, γ-HCH (lindane), αendosulfan, βendosulfan and Endosulfansulfate. The samples were collected seasonally between the monthsof July 2012 and April 2013. The residue levels of organochlorine pesticides in air samples during month of October ranged between0.027±0.004 to5.735±0.575 ng/M 3 , while during the Month of February the concentration ranged between 0.013±0.00 to 9.375±1.65 ng/M 3 and the levels during the month of April ranged between 0.013±0.00 to 11.508±0.26ng/M 3 . Organochlorine pesticide detected in soil during month of October ranged between BDL to 131.206 ± 14.41ng/Kg, while during the Month of February the concentration ranged between 0.418± 0.01to 38.361 ±5.39 ng/Kg and the levels during the month of April ranged between 0.406± 0.00to 26.877± 8.89 ng/Kg. The residue levels of the analysedPOPs in air and soil were generally high at the Dandora and Industrial area sites. This indicates that industrial activities such as Tetra-Pac, general plastics, Phillips industries waste and stock piles are the main sources of the new POPs in Nairobi. The high concentration level poses a health risk to residents of Dandora and Industrial area workers.
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