加料速率对鼓泡流化床木屑催化热解的影响

Nanhang Dong, S. Gu, K. Papadikis, L. Armstrong, K. Luo
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引用次数: 0

摘要

采用原位催化剂对鼓泡流化床中木屑的催化裂化进行了数值研究。生物油的提质是生物质热解产物应用的关键问题之一。由于多相流动力学与化学反应的相互作用,生物质热化学处理的计算模型可能相当复杂。本文主要研究了木屑热解制备生物油的在线催化升级工艺。采用欧拉-欧拉模型结合颗粒流动力学理论对流化床内的多相流进行了模拟。基于化学动力学,建立了用户定义函数(UDF)来表示生物质的分解和生物油的升级。模拟结果表明,非均相反应对流化床流体力学性能有显著影响,不同时空、催化剂质量与焦油流量之比会改变产物的产率分布。
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Effects of feeding rate on catalytic pyrolysis of sawdust in bubbling fluidized beds
Catalytic cracking of sawdust has been studied numerically in bubbling fluidized beds with in situ catalyst. The upgrading of bio-oil is one of the critical issues in applications of biomass pyrolysis products. Due to the interactions of multiphase flow dynamics coupled with chemical reaction, computational modelling of thermo-chemical processing of biomass can be quite complex. In current work, the online catalytic upgrading of bio-oil derived by sawdust pyrolysis is investigated. The Eulerian-Eulerian models coupled with the Kinetic Theory of Granular Flows are employed to model the multiphase flow in fluidized beds. The user defined functions (UDF) is developed based on the chemical kinetics to represent the decomposition of biomass and upgrading of bio-oil. The simulation results show that the heterogeneous reactions can perform significant effects on hydrodynamics of fluidized beds while different space time, the ratio of catalyst mass to tar flow rate, will vary the yield distribution of products.
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