用金属氧化物纳米团簇修饰的聚合物薄膜中的光定位

S. Yastrebov, Xenia V. Izotova, O. Babkin, Mahi R. Singh
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引用次数: 0

摘要

本文介绍了纳米金属氧化物光聚合环氧丙烯酸酯组合物的研究结果。结果表明,当氧化锌固相含量为4 wt.%时,有可能获得具有发光效果的组合物。提出了光在具有色散散射体的聚合物基体中扩散运动的图形模型,并对产生发光的条件进行了数学计算。在实验和计算的基础上,对将获得的材料作为一种超材料的前景进行了假设,这种材料的使用将决定在使用UV固化技术固化系统期间产生的晶体准结构的性质。
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LOCALIZATION OF LIGHT IN POLYMER FILMS, MODIFIED WITH METAL OXIDE NANOCLUSTERS
The article describes the results of studies of photopolymerizable epoxyacrylate compositions containing nanometer-sized additions of metal oxides. The results obtained showed the possibility of obtaining compositions that have the effect of luminescence when the content of the solid phase of zinc oxide is 4 wt.%. A graphical model is proposed that reflects the picture of the diffusion motion of light inside a polymer matrix with a dispersive light scatterer, and a mathematical calculation of the conditions for the appearance of luminescence is carried out. On the basis of the experiments and calculations performed, an assumption was made about the prospects of considering the obtained material as a meta-material, the use of which will determine the properties of the crystalline quasi-structure that arise during the curing of the system using the UV- curing technology.
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