合成杂环有机化合物的结构、光学和热表征

Arpitha Kumari, G. Sanjeev, Boja Poojari, P. Soumya
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引用次数: 0

摘要

采用Claisen-Schmidth缩合反应合成了3-[(2z)-2-甲基-3-(4-硝基苯)丙-2-烯基]- 2h -(1-苯并吡喃-2-酮)(MNB)杂环有机化合物。结构表征和官能团的存在分别进行了粉末x射线衍射和红外光谱研究。通过热重分析和差热分析确定了该有机晶体的熔融性能,结果表明该有机晶体在166℃时具有良好的热稳定性。利用Nd: YAG激光器进行了二次谐波产生效率的研究,表明该化合物具有良好的NLO表征和光电子学应用前景。可见区存在PL波长,表明样品具有荧光特性。
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Structural, Optical and Thermal Characterization of Synthesised Heterocyclic Organic Compound
A heterocyclic organic compound of 3-[(2z)-2-methyl-3-(4-nitrophenyl) prop-2-enoyl]-2H-(1-benzopyran-2-one) (MNB) is synthesized using Claisen-Schmidth condensation reaction. Structural characterization and presence of functional groups are carried out using powder X-ray diffractogram and FTIR spectroscopic studies respectively. Thermogravimetric analysis and differential thermal analysis are carried out to determine the melting property and it shows good thermal stability among organic crystal showing result at 166°C. Second Harmonic Generation efficiency study is carried out using Nd: YAG laser, this revealed that titled compound is good for NLO characterization and applicable in optoelectronics. PL wavelength present in visible region conclude that sample shows fluorescence property.
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