合成TiO2纳米颗粒光催化降解水中2,4-二氯苯氧乙酸

Dung Le Thi, L. Nguyen Quynh, T. Nguyen Duc, Son Le Thanh, Duc Pham Tien
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摘要

本研究利用合成的二氧化钛纳米粒子(TiO2-NPs)研究了在水环境下对2,4-二氯苯氧乙酸(2,4- d)的光降解。通过x射线衍射(XRD)、透射电子显微镜(TEM)、红外光谱(IR)和zeta电位测量对溶胶-凝胶法制备的TiO2-NPs进行了表征。结果表明:TiO2 - NPs为粒径约为30nm的纳米微球,主要为锐钛矿相;合成的TiO2-NPs的零电荷点(PZC)在6.0左右。考虑光催化降解2,4- d的有效条件为120 min, pH为11,KCl为1 mM。在理想条件下,2,4- d的光降解效率可达72%以上。我们的结果表明,TiO2-NPs有望应用于从水溶液中去除2,4- d。
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Photocatalysis degradation of 2,4-dichlorophenoxyacetic acid in water environment using synthesized TiO2 nanoparticles
The present study investigated the photodegradation of 2,4-Dichlorophenoxyacetic acid (2,4-D) in a water environment using synthesized titania nanoparticles (TiO2-NPs). The TiO2-NPs fabricated by sol-gel method were distinguished by X-ray diffraction (XRD) and Transmission electron microscopy (TEM), Infrared spectroscopy (IR), and zeta potential measurements. The results indicated that TiO2 - NPs were nanospheres of appropriately 30nm with a major anatase phase. Synthesized TiO2-NPs have the point of zero charge (PZC) of around 6.0. The efficient conditions for photocatalysis degradation of 2,4-D under sunlight were considered and found to be 120 min, pH 11, and 1 mM KCl. Under ideal conditions, the photodegradation efficiency of 2,4-D reached greater than 72 %. Our results suggest that TiO2-NPs would be promisingly applied for eliminating 2,4-D from an aqueous solution.
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