用伏安分析仪测定溶液中金属离子浓度

B. Begenova, K. Khakimbolatova, N.V. Ostafeychuk
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摘要

离子交换材料成功地应用于解决生产工艺无废技术创新、工业废水处理、合理利用自然资源和环保利用等一系列实际问题。离子交换剂的物理化学和吸附特性研究是确定离子交换剂应用前景的必要条件,但化学研究方法繁琐,原子吸收光谱技术也不成熟。这项工作的目的是寻找和使用现有的方法,不需要复杂的技术设备来测定溶液中的金属离子浓度。方法。采用加法溶出伏安法测定溶液中金属离子的平衡浓度。结果和讨论。有色金属离子浓度的测定方法已经开发出来,并在伏安分析仪«Ecotest BA»上使用,这是一个真正经济的替代昂贵的分析方法。含镉和铜、锌、铅阳离子样品的溶出伏安图;构建了钒酸盐离子、钼酸盐离子。计算了吸附后平衡溶液中的离子浓度。结论。溶出伏安法便于研究吸附和离子交换材料的络合性能;它还可以在不进行初步分离的情况下确定几种金属。
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THE METAL IONS CONCENTRATION DETERMINING IN THE SOLUTIONS USING VOLTAMMETRIC ANALYZER
Ion exchange materials are successfully used for solution of a number of practical problems, such as production processes waste-free technology creation, industrial wastewater treatment, rational natural resources and environmental protection use. The Physicochemical and sorption characteristics study is needed for the determination of ion exchangers application promising areas, however chemical research methods are laborious, and atomic absorption spectroscopy is not always available. The purpose of this work is to find and use available methods, which do not require complex technological equipment for metal ions concentration determining in the solutions. Methodology. Stripping voltammetric determination of metal ions by addition method has been used to determine the equilibrium concentrations of metal ions in the solutions. Results and discussion. The non-ferrous metal ions concentration determining methods have been developed and used on the voltammetric analyzer «Ecotest BA», which is a real economical alternative to expensive methods of analysis. Stripping voltammograms of samples, which contain cadmium and copper, zinc, lead cations; vanadate ion, molybdate ion were constructed. The ions concentrations in the equilibrium solutions after sorption are calculated. Conclusion. The stripping voltammetric method is convenient for studying the sorption and ion-exchange materials complexing properties; it and also allows to determine several metals without their preliminary separation resorting.
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