淀粉基木材胶粘剂的硅烷改性研究进展

Ravindra V. Gadhave, Praneeta Sheety, P. Mahanwar, P. Gadekar, Bilvesh J. Desai
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引用次数: 15

摘要

目前,人们对用生物基可再生聚合物代替传统合成聚合物作为粘合剂的应用越来越感兴趣。然而,像淀粉这样的生物基可再生聚合物几乎没有什么缺点,比如耐水性和机械强度差。要成为合成聚合物的重要潜在替代品,淀粉必须具有与合成聚合物相当的物理、化学、热学和机械性能。为此,对淀粉进行了硼酸、柠檬酸、乙二醛、gluteraldehyde等一系列交联剂改性和硅烷改性。采用氯丙基三甲氧基硅烷、γ-甲基丙烯氧基三甲氧基硅烷和乙烯基三甲氧基硅烷对硅烷进行改性是一种从力学性能和热性能两方面改善硅烷的合适方法。硅烷在淀粉改性过程中与淀粉形成共价键,从而提高了淀粉的剪切强度和储存稳定性。以多种硅烷为原料制备了可生物降解、可再生、环保的淀粉基木材胶粘剂硅烷改性研究。本文综述了硅烷作为淀粉基木材胶粘剂的改性剂。
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Silane Modification of Starch-Based Wood Adhesive: Review
Currently there has been a growing interest in substituting traditional synthetic polymers with biobased renewable polymers for adhesive applications. However, biobased renewable polymers such as starch suffer from few draw-backs like poor water resistance and mechanical strength. To become important potential alternatives of synthetic polymers, starch must have comparable physical, chemical, thermal and mechanical properties to that of synthetic polymers. To achieve this, starch has been modified by a series of crosslinkers like boric acid, citric acid, glyoxal, gluteraldehyde, etc. and silane modification. Silane modification by chloropropyl trimethoxysilane, γ-Methacryloxypropyl trimethoxy silane and vinyl trimethoxy silane is a suitable method to improve the performance in terms of mechanical and thermally. Silane forms covalent bonds with starch during starch modification resulted in enhanced shear strength and storage stability. A new research on biodegradable, renewable, environmentally friendly silane modification of starch-based wood adhesive that was prepared by reacting with various silanes. This paper, we reviewed silane as a modifying agent for starch-based wood adhesive.
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