生物炭(生物炭)对抗静电包装用增塑聚乳酸复合材料性能的影响

N. Ali
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引用次数: 7

摘要

采用喷雾干燥法制备了粒径为21.7 nm的聚乳酸可生物降解抗静电包装膜,制备了新型轻质纳米碳。生物碳(生物炭)是从植物和土壤中获得的,可以自然地吸收和储存大气中的二氧化碳。因此,它被用于支持可生物降解的聚乳酸(PLA),以获得100%可回收的材料。以聚乳酸百里香酚和生物炭(生物炭)为复合材料,采用(0.5 ~ 10)wt%的生物炭溶液浇铸法制备了增塑剂。通过红外光谱(FTIR)、电导率、力学性能、接触角、光亮度等对复合材料进行表征。结果表明,随着生物炭含量的增加,复合材料的导电性提高,使其电阻率降低,适合用于电子元件的运输和储存的防静电包装;力学试验表明,由于使用百里香酚作为增塑剂,PLA/百里香酚(95/5)的拉伸强度和拉伸模量降低,但伸长率、抗撕裂性和硬度增加,薄膜复合材料由脆性变为韧性。纯PLA的接触角为83◦,即为疏水材料,PLA/百里香酚/生物炭10%时,接触角降至54◦,获得了能够消散或促进静电衰减的亲水材料,提高了电子器件的加工能力。颜色和亮度等光学指标显示,在10%生物炭时,颜色和亮度下降,但适合抗静电包装,变得不透明。
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Characterization of biochar (bio carbon) on the properties of plasticized polylactic acid composites for antistatic packaging
A new  light-weight nanocarbon prepared by spray-drying method  to obtain  particle size is 21.7 nm based of polylactic acid biodegradable film in antistatic packaging .Bio carbon (biochar) is  obtained from  plants and soils to naturally absorb and store carbon dioxide from the atmosphere . Therefor it has been used to support biodegradable polylactic acid (PLA) with to obtain 100% recyclable material. Using plasticizer thymol of polylactic acid and biochar (bio carbon) as composites were prepared by a solution casting method with (0.5-10)wt% biochar. The composites  characterized by  FTIR, electrical conductivity, mechanical properties , contact angle and Colar and Brightness . Results show that electrical conductivity of increased with increased biochar and makes the composite lower resistive and appropriate for use as antistatic packaging for the transportation and store of electronic components, mechanical tests show reduced the tensile strength and   tensile modulus but increased in  elongation, Tear Resistance and Hardness because used thymol as plasticizers  at PLA/thymol  (95/5) and films composites change from brittle to ductile   . The results of contact angle of pure PLA is 83◦ that mean hydrophobic materials and decreased to 54◦ at PLA/thymol/biochar 10% to obtain hydrophilic materials that able to dissipate or promote the decay of static electricity and improve process ability of electronic device. Optical such as Color and Brightness show that decreased but suitable for antistatic packaging   and became opacity at 10% biochar.  
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