新型GdxCo3O4纳米结构的合成、形貌及增强光学性能

V. Adimule, B. Yallur, S. Batakurki, Santosh S Nandi
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引用次数: 6

摘要

摘要:本文采用共沉淀法合成了1 wt. %、5 wt. %和10 wt. %的钆掺杂氧化钴纳米结构。采用扫描电子显微镜(SEM)、x射线衍射光谱(XRD)、紫外可见光谱(UV-Visible spectroscopy)对样品进行了表征。Gd(10% wt)Co3O4在440.81 nm处表现出最大的紫外-可见光吸收,通过Tauc图计算带隙能,发现随着Gd掺杂率的增加,带隙能从7.74 eV下降到2.64 eV。与Gd(1% wt)Co3O4 NS相比,Gd(10% wt)Co3O4 NS的结晶度提高。SEM形貌显示,Co3O4纳米颗粒的平均粒径在95 ~ 78 nm之间,分布均匀。
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Synthesis, Morphology and Enhanced Optical Properties of Novel GdxCo3O4 Nanostructures
Abstract: In the present studies, gadolinium doped cobalt oxide nanostructures (1 wt. %, 5 wt. % and 10 wt. %) were synthesized by co-precipitation method. The samples were characterized by SEM (scanning electron microscopy), XRD (X-ray diffraction spectroscopy), UV-Visible spectroscopy. UV-Visible exhibited maximum absorption at 440.81 nm for Gd(10% wt)Co3O4 Band gap energy was calculated using Tauc plots and it was observed that band gap energy decreased from 7.74 eV to 2.64 eV upon increasing the doping percentage of Gd to Co3O4. The crystallinity of the Gd(10% wt) Co3O4 NS increased as compared with Gd(1% wt)Co3O4 NS. SEM morphology revealed average particle size were between 95 nm to 78 nm uniformly distributed over Co3O4 NS.
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