Agus Sundaryono, Arsela Eko Listiono, M. Firdaus, D. Handayani
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摘要

棕榈油厂废水(POME)是棕榈油厂鲜果串加工(FFB)过程中产生的废液。POME含有0.7%的油渣(来自处理过的FFB)。本研究的目的是利用超声波辐照和催化裂化技术,将POME的油渣转化为生物汽油。在超声波照射下,将POME的油渣与甲醇进行酯化和酯交换反应,实现了POME的转化。该反应产物采用Ni/HZa和Mo-Ni/HZa两种分子筛基催化剂进行催化裂化反应。采用气相色谱法对反应结果进行表征。使用Mo-Ni/HZa催化剂发现的组分为51.22%的生物汽油和其他煤油、柴油产品以及长链甲酯组分,而使用Ni/HZa催化剂发现的组分相当于柴油的2.44%。关键词:生物汽油,超声波辐照,催化裂化,沸石催化剂,POME
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KONVERSI KONVERSI BIOGASOLIN DARI RESIDU MINYAK PALM OIL MILLS EFFLUENT (POME) DENGAN BANTUAN IRADIASI ULTRASONIK DAN PERENGKAHAN KATALITIK
Palm oil mill effluent (POME) is a liquid waste by product of fresh fruit bunches processing (FFB) in palm oil factory (POF). POME contains oil residue of 0.7% (from treated FFB). The purpose of this study was to convert oil residue of POME into biogasolin with the help of ultrasonic irradiation and catalytic cracking. The convertion was performed by reacting oil residue of POME with methanol in an esterification and transesterification reaction with the aid of ultrasonic irradiation. The reaction product was further reacted in the catalytic cracking reaction using zeolite-based catalysts (Ni/HZa and Mo-Ni/HZa). The overall reaction results were characterized using GCMS to determine the constituent components. The components  found using Mo-Ni/HZa catalyst were 51.22% biogasoline and other products of kerosene and diesel as well as long chain methyl ester components, whereas using Ni/HZa catalyst was found a component equivalent to diesel at 2.44%. Keywords: biogasoline, ultrasonic irradiation, catalytic cracking, zeolite catalyst, POME
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