紫硬石漂白、填充、染色的鉴定特征

Y. Lu, D. Hui, Li Liujie, Cao Suqiao, Wang Feng, Guo Lianqiao, Yu Zhen
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摘要

采用宝石显微镜、折光仪、紫外-可见-近红外光谱仪、XRF光谱仪、DiamondViewTM光谱仪、FTIR光谱仪和拉曼光谱仪对漂白、填充、染色后的紫翡翠进行鉴定。结果表明:经漂白、填充、染色处理后的紫色翡翠样品内部结构被破坏,并通过红外光谱仪和拉曼光谱仪检测到环氧树脂。1 596 cm-1处的强拉曼峰可以作为染料的特征峰。发光图像显示环氧树脂和有机染料形成的聚合物具有典型的蓝紫色荧光。经漂白、填充和染色处理的紫色翡翠样品紫外可见光谱显示,吸收波段在200 ~ 350 nm,吸收峰在409 nm,吸收波段在569 nm附近。被紫色抛光粉染色的翡翠内部结构没有被破坏,由于粉末颗粒只残留在表面,所以紫色只在表面染色。发光图像显示粉红色的紫色荧光,这是由紫色抛光粉引起的。在紫外-可见光谱中可见到558 nm处的强中心吸收带和611 nm处的弱中心吸收带,与天然紫玉不同。
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Identification Characteristic of Purple Jadeite Treated with Bleaching, Filling and Dyeing
To explore the identification characteristics of purple jadeite that is treated with bleaching, filling and dyeing, the gem microscope, refractometer, UV-Vis-NIR spectropho-tometer, XRF spectrometer, DiamondViewTM, FTIR and Raman spectrometer were used. The results showed that the internal structure of the purple jadeite samples treated with bleaching, filling and dyeing was destroyed, and epoxy resin was detected by infrared spectrometer and Raman spectrometer. Strong Raman peak at 1 596 cm-1 could be the characteristic peak of dyes. Luminescent images showed the characteristic blue-violet fluorescence of the polymers formed by epoxy resin and organic dyes. The UV-Vis spectra of the purple jadeite samples treated with bleaching, filling and dyeing showed the absorption band of 200-350 nm, the absorption peak at 409 nm and the absorption band near 569 nm.The internal structure of the jadeite stained by the purple polishing powder was not damaged, and the purple colour only stained on the surface since the powder particles only remained on the surface. The luminescent images showed pinkish purple fluorescence, which was caused by the purple polishing powder. The strong central absorption band at 558 nm and the weak central absorption band at 611 nm can be seen in the UV-Vis spectra, which are different from the natural purple jadeite.
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