{"title":"碳硼烷簇的配位化学:碳硼烷、碳硼酰和碳硼烷配合物中的金属-硼键","authors":"Bennett J. Eleazer, D. V. Peryshkov","doi":"10.1080/02603594.2018.1465939","DOIUrl":null,"url":null,"abstract":"Metalated three-dimensional icosahedral boron clusters often exhibit high chemical and thermal stability relative to their simple borane counterparts thus making them a convenient object to study the chemistry of metal-boron bonds. The presence of multiple reactive boron vertices makes carboranes unique ligands with unusual steric and electronic requirements. This article summarizes recent developments in coordination chemistry of neutral {C2B10} carborane clusters with a focus on metal-boron interactions. Several bonding modes are discussed, including neutral borane coordination through bridging B–H··· M interactions, boryl complexes with B -M bonds, multimetallic assemblies, and the BB-carboryne complex containing a three-membered (BB)>Ru metallacycle.","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"63 1","pages":"109 - 79"},"PeriodicalIF":3.8000,"publicationDate":"2018-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"31","resultStr":"{\"title\":\"Coordination Chemistry of Carborane Clusters: Metal-Boron Bonds in Carborane, Carboranyl, and Carboryne Complexes\",\"authors\":\"Bennett J. Eleazer, D. V. Peryshkov\",\"doi\":\"10.1080/02603594.2018.1465939\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Metalated three-dimensional icosahedral boron clusters often exhibit high chemical and thermal stability relative to their simple borane counterparts thus making them a convenient object to study the chemistry of metal-boron bonds. The presence of multiple reactive boron vertices makes carboranes unique ligands with unusual steric and electronic requirements. This article summarizes recent developments in coordination chemistry of neutral {C2B10} carborane clusters with a focus on metal-boron interactions. Several bonding modes are discussed, including neutral borane coordination through bridging B–H··· M interactions, boryl complexes with B -M bonds, multimetallic assemblies, and the BB-carboryne complex containing a three-membered (BB)>Ru metallacycle.\",\"PeriodicalId\":10481,\"journal\":{\"name\":\"Comments on Inorganic Chemistry\",\"volume\":\"63 1\",\"pages\":\"109 - 79\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2018-05-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"31\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comments on Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/02603594.2018.1465939\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comments on Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/02603594.2018.1465939","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Coordination Chemistry of Carborane Clusters: Metal-Boron Bonds in Carborane, Carboranyl, and Carboryne Complexes
Metalated three-dimensional icosahedral boron clusters often exhibit high chemical and thermal stability relative to their simple borane counterparts thus making them a convenient object to study the chemistry of metal-boron bonds. The presence of multiple reactive boron vertices makes carboranes unique ligands with unusual steric and electronic requirements. This article summarizes recent developments in coordination chemistry of neutral {C2B10} carborane clusters with a focus on metal-boron interactions. Several bonding modes are discussed, including neutral borane coordination through bridging B–H··· M interactions, boryl complexes with B -M bonds, multimetallic assemblies, and the BB-carboryne complex containing a three-membered (BB)>Ru metallacycle.
期刊介绍：
Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts.
Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.
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