库址不同天然地下水的腐蚀、化学和微生物群落比较

M. Somervuori, E. Isotahdon, Maija Nuppunen-Puputti, M. Bomberg, L. Carpén, P. Rajala
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引用次数: 2

摘要

在芬兰,低水平和中水平放射性废物(LLW和ILW)的储存库将位于大约60至100米深的花岗岩基岩中的三个不同的地理位置,在那里,废物和废物容器可以受到含有微生物的缺氧地下水的影响。地下水的组成在不同地点的化学成分和微生物活动方面有所不同。本研究对3个库区地下水的化学成分和微生物群落进行了分析。采用电化学方法研究了碳钢AISI/ sae1005和不锈钢AISI 304、316L在地下水环境中的腐蚀倾向。作为参考,在没有微生物的模拟地下水中也进行了测量。测量结果表明,水的腐蚀性和钢的性能因水的来源而异。此外,地下水的化学成分、微生物群落的丰度和多样性也存在显著差异。因此,在评价处置概念的长期演变时,必须考虑到当地的环境。
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A Comparison of Different Natural Groundwaters from Repository Sites—Corrosivity, Chemistry and Microbial Community
In Finland, the repositories for low and intermediate-level radioactive waste (LLW and ILW) will be situated at three different geographical locations in about 60 to 100 m deep granite bedrock where the waste and waste containers can be subjected to anoxic groundwater containing microbes. The composition of groundwater varies in terms of chemistry and microbial activity in different locations. In this study, groundwater from the three repository areas was analyzed in respect to chemistry and microbial community. Corrosion tendency of three steel grades, carbon steel AISI/SAE 1005 and stainless steels AISI 304 and 316L, was studied in these groundwater environments using electrochemical methods. As a reference, measurements were also performed in simulated groundwater without microbes. The measurements show that corrosivity of the water and thus the steels’ performance differs depending on water origin. In addition, the groundwater differed remarkably in their chemical composition as well as abundance and diversity of microbial community between the sites. Consequently, the local environment has to be considered when evaluating the long-term evolution of disposal concepts.
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