聚砜酰胺静电纺丝纳米纤维的制备

Li Liu, Yinggang Shi, Qinghua Jiao, Yanan Wu, Zhikun Zhang, J. Liu
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引用次数: 1

摘要

本文采用静电纺丝技术制备聚磺胺纳米纤维。以4,4′-二氨基二苯基砜和对苯二酰氯为原料,在N,N-二甲基乙酰胺(DMAc)为常用溶剂,采用低温溶液缩聚法制备了具有较高固有粘度的聚磺酰胺。研究了溶液浓度、工艺参数(电压、针尖到集电极的距离)对溶液可纺性和静电纺聚砜纶纤维形态的影响。利用扫描电子显微镜(SEM)定量研究了静电纺聚砜纶纤维的微观结构与工艺参数的关系。
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Preparation of polysulfoneamide electrospinning nanofibers
In this paper, we select electrospinning technique to fabricate polysulfonamide nanofibers. Polysulfonamide with relatively high inherent viscosity was prepared based on 4,4'-diaminodiphenylsulfone and terephthaloyl chloride in the common solvent N,N-Dimethylacetamide (DMAc) by the method of low-temperature solution condensation polymerization. Our research work focused on studying the effect of concentration of solution, processing parameters including voltage and distance from tip to collector on the spinnability of the solution and morphology electrospun polysulfonamid fibers. The microstructures of the electrospun polysulfonamid fibers were quantitively investigated by scanning electron microscope (SEM) as a function of processing variables.
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