白俄罗斯电气设备废塑料中污染物的含量

T. Kukharchyk, V. D. Chernyuk, V. P. Kulakovich
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引用次数: 2

摘要

. 电子和电气设备废塑料的管理问题,一方面与其形成量的增加和回收利用的“绿色”循环经济要求有关,另一方面与其中所含的有害物质,包括持久性有机污染物和重金属有关。本文介绍了在明斯克的企业收集和加工的电子电气设备塑料样品中污染物含量的测量结果。用x射线荧光光谱法测定了40个塑料样品中的重金属和溴的含量,用多溴联苯(PBBs)和多溴联苯醚(PBDEs)测定了19个样品中的气相色谱质谱检测。结果表明,40%的样品中记录了铅的含量(最大值为259毫克/公斤塑料),28%的样品中记录了镉(22毫克/公斤),20%的样品中记录了铬(98毫克/公斤);汞和多溴联苯含量均低于检测限。7.5%的样品中含有多溴二苯醚,范围在246-6615毫克/公斤。十溴联苯醚是一种持久性有机污染物,占总多溴联苯醚的89 ~ 96%。发现含溴塑料的比例很高(48%),这与其他国家的数据一致。讨论了在白俄罗斯开展研究,扩大废塑料中已分析污染物清单的必要性,以及根据《关于持久性有机污染物的斯德哥尔摩公约》的义务发展与废塑料管理有关的监管和技术基础的必要性。
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Content of pollutants in waste plastic of electrical equipment in Belarus
. The problem of management of waste plastic of electronic and electrical equipment (EEE) is associated, on the one hand, with the increase in the volume of their formation and the “green” circulation economy requirements for recycling, and, on the other hand, with the hazardous substances contained in them, including persistent organic pollutants (POPs) and heavy metals. The article presents the measurement results of the content of pollutants in EEE plastic samples taken at the enterprises for their collection and processing in Minsk. The content of heavy metals and bromine was determined in 40 plastic samples using X-ray fluorescence spectrometry, polybrominated biphenyls (PBBs) and of polybrominated diphenyl ethers (PBDEs) – in 19 samples using gas chromatography with mass spectrometric detection. It was shown that the content of lead was recorded in 40 % of samples (the maximum value is 259 mg/kg of plastic), of cadmium – 28 % (22 mg/kg), of chromium – 20 % (98 mg/kg); the content of mercury and PBB was found to be below the detection limit. PBDEs are contained in 7.5 % of samples in the range 246–6615 mg/kg. Decabromodiphenyl ether, a persistent organic pollutant, accounted for 89 to 96 % of the total PBDE. A high proportion of bromine-containing plastic (48 %) was revealed, which is consistent with the data of other countries. The need to carry out research in Belarus with the expansion of a list of analyzed pollutants in waste plastic and to develop the regulatory and technical base in relation to the management of waste plastic in accordance with the obligations of the Stockholm Convention on POPs is discussed.
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