{"title":"1RS,4SR,7SR,10RS-(1,4,7,10-四氮杂环十五烷)铜(II)四氯辛酸盐的制备与结构","authors":"N. F. Curtis, J. Wikaira","doi":"10.1080/2164232X.2013.868325","DOIUrl":null,"url":null,"abstract":"The structure of 1RS,4SR,7SR,10RS-(1,4,7,10-tetraazacyclopentadecane)copper(II) tetrachlorozincate, determined at 120 K, is reported: C11H26Cl4CuN4Zn, orthorhombic, P b c a (Hall−P 2ac 2ab); a, 14.0675(7); b, 14.4206(6); c, 18.2106(10) Å. The cation has approximate two-fold symmetry, with the CuN4 group tetrahedrally twisted, with NH groups alternating on opposite sides of the N4 group around the ring. The five-membered chelate rings have gauche conformations and the eight-membered chelate ring has an extended twist conformation. The anion and cation are linked into chains by hydrogen bonds and weak Cu···Cl interactions.","PeriodicalId":10590,"journal":{"name":"Complex Metals","volume":"109 3","pages":"3 - 6"},"PeriodicalIF":0.0000,"publicationDate":"2014-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Preparation and structure of 1RS,4SR,7SR,10RS- (1,4,7,10-tetraazacyclopentadecane)copper(II) tetrachlorozincate\",\"authors\":\"N. F. Curtis, J. Wikaira\",\"doi\":\"10.1080/2164232X.2013.868325\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The structure of 1RS,4SR,7SR,10RS-(1,4,7,10-tetraazacyclopentadecane)copper(II) tetrachlorozincate, determined at 120 K, is reported: C11H26Cl4CuN4Zn, orthorhombic, P b c a (Hall−P 2ac 2ab); a, 14.0675(7); b, 14.4206(6); c, 18.2106(10) Å. The cation has approximate two-fold symmetry, with the CuN4 group tetrahedrally twisted, with NH groups alternating on opposite sides of the N4 group around the ring. The five-membered chelate rings have gauche conformations and the eight-membered chelate ring has an extended twist conformation. The anion and cation are linked into chains by hydrogen bonds and weak Cu···Cl interactions.\",\"PeriodicalId\":10590,\"journal\":{\"name\":\"Complex Metals\",\"volume\":\"109 3\",\"pages\":\"3 - 6\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Complex Metals\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/2164232X.2013.868325\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Complex Metals","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/2164232X.2013.868325","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation and structure of 1RS,4SR,7SR,10RS- (1,4,7,10-tetraazacyclopentadecane)copper(II) tetrachlorozincate
The structure of 1RS,4SR,7SR,10RS-(1,4,7,10-tetraazacyclopentadecane)copper(II) tetrachlorozincate, determined at 120 K, is reported: C11H26Cl4CuN4Zn, orthorhombic, P b c a (Hall−P 2ac 2ab); a, 14.0675(7); b, 14.4206(6); c, 18.2106(10) Å. The cation has approximate two-fold symmetry, with the CuN4 group tetrahedrally twisted, with NH groups alternating on opposite sides of the N4 group around the ring. The five-membered chelate rings have gauche conformations and the eight-membered chelate ring has an extended twist conformation. The anion and cation are linked into chains by hydrogen bonds and weak Cu···Cl interactions.
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