加速器质谱分析:可持续发展社会的分析工具。

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-01-01 DOI:10.1140/epjti/s40485-023-00088-3
William E Kieser
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引用次数: 0

摘要

加速器质谱法(AMS)在同位素比质谱法(IRMS)的基本原理基础上增加了高能带电粒子加速技术,为小至1毫克的天然材料样品中的稀有同位素提供极低的检测能力(低于1飞图)。根据所选择的元素和设备的配置,稀有同位素的灵敏度可以达到小于1015分之一。这种小样本量和高灵敏度检测稀有同位素的优点包括:a)收集、运输和制备小得多的样品的经济效益;b)分析样品中特定化合物的能力。对于后一种优势,可以更精确地追踪该化合物通过复杂系统的途径,或者在放射性同位素的情况下,可以提供更精确的时间信息。该文件是原子能机构研究和可持续发展加速器国际会议上提出的材料的放大版:新概念和技术革新。首先介绍了AMS技术的基本概况,重点介绍了高能量的使用如何有助于提高灵敏度,然后提供了几个新的AMS技术的例子,这些技术减少了此类系统的能量和空间要求。然后简要描述了有助于在其他环境问题领域调查可持续性的几个应用实例。
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Accelerator mass spectrometry: an analytical tool with applications for a sustainable society.

Accelerator Mass Spectrometry (AMS) adds the techniques of higher energy charged particle acceleration to the basic principles of Isotope Ratio Mass Spectrometry (IRMS) to provide extremely low detection capability (below 1 femtogram) of rare isotopes in samples of natural materials as small as 1 mg. Depending on the element selected and the configuration of the equipment, rare isotope sensitivities can reach less than one part in 1015. The advantages of this small sample size and high sensitivity for the detection of rare isotopes include a) the economic benefit of collecting, shipping and preparing much smaller samples, and b) the ability to analyse specific chemical compounds within the sample. For the latter advantage, the pathway taken by that compound through a complex system can be more precisely traced or, in the case of radioactive isotopes, more precise chronological information can be provided. The paper is an amplification of material which was presented at the IAEA International Conference on Accelerators for Research and Sustainable Development: novel concepts and technical innovation. It begins with a basic overview of AMS technology, with an emphasis on how the use of higher energy contributes to this enhanced sensitivity, and then provides several examples of new AMS technologies which reduce the energy and space requirements for such systems. Several examples of applications which contribute to the investigation of sustainability in other areas of environmental concern are then briefly described.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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