几种含吡唑片段的活性三嗪偶氮染料的染色性能研究。

IF 1.7 4区 化学 Q3 CHEMISTRY, ORGANIC Current organic synthesis Pub Date : 2023-05-05 DOI:10.2174/1570179420666230505094803
Alaa Z Omar, Mohamed G Mohamed, Ezzat A Hamed, Mohamed A El-Atawy
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引用次数: 0

摘要

合成了一系列含偶氮和三聚氰胺的分散活性染料,并通过光谱和元素分析确定了它们的结构。方法:红外光谱(IR)、核磁共振(1H NMR)和离散傅立叶变换(DFT)研究表明,所制备的活性分散染料主要以腙互变异构体存在。观察了甲醇中的电子吸收光谱,并与B3LYP/6-311G(d,p)计算的电子吸收光谱进行了比较。考察了所制备的分散活性染料在涤纶、棉和涤棉混纺织物上的染色效果。结果:对染色样品的排汗、耐洗、耐焦、耐光牢度进行了测定。实验结果表明,活性分散染料对涤纶织物的染色效果优于棉织物。结论:对合成染料的反射率和显色强度进行了测定和讨论。
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Investigation of the Dyeing Ability of Some Reactive Triazine Azo Dyes Containing Pyrazole Fragment.

A series of dispersed reactive dyes bearing azo and cyanuric groups were synthesized, and their structures were established using spectral and elemental analyses.

Method: The IR, 1H NMR, and DFT studies indicated that the prepared reactive disperse dyes predominately exist as hydrazone tautomers. The electronic absorption spectra in methanol were observed and compared to those computed using B3LYP/6-311G(d,p). The dyeing efficiency of the produced dispersed reactive dyes was examined on polyester, cotton, and polyester/cotton blended fabrics.

Results: The degree of exhaustion and the quick properties of the dyed samples in terms of perspiration, washing, scorch and light fastness were assessed. It was found that reactive disperse dyes under investigation have a higher affinity for dyeing polyester textiles than cotton textiles.

Conclusion: Moreover, the reflectance and color strength of the synthesized dyes were measured and discussed.

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来源期刊
Current organic synthesis
Current organic synthesis 化学-有机化学
CiteScore
3.40
自引率
5.60%
发文量
86
审稿时长
6-12 weeks
期刊介绍: Current Organic Synthesis publishes in-depth reviews, original research articles and letter/short communications on all areas of synthetic organic chemistry i.e. asymmetric synthesis, organometallic chemistry, novel synthetic approaches to complex organic molecules, carbohydrates, polymers, protein chemistry, DNA chemistry, supramolecular chemistry, molecular recognition and new synthetic methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by experts who are internationally known for their eminent research contributions. The journal is essential reading to all synthetic organic chemists. Current Organic Synthesis should prove to be of great interest to synthetic chemists in academia and industry who wish to keep abreast with recent developments in key fields of organic synthesis.
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