开放式动态协调电池正则电极上最佳电压的解析解。

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-04-01 Epub Date: 2023-03-15 DOI:10.1177/14690667231164552
Anton Lioznov, Evgeny Nikolaev
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引用次数: 0

摘要

傅立叶变换离子回旋共振法在质量精确度和分辨能力方面领先于所有其他质谱分析方法。傅立叶变换离子回旋共振法之所以能在质量精确度和分辨力方面遥遥领先,主要归功于其动态协调池。在对快速回旋运动进行平均后,该样品池具有理想的双曲线俘获势能。最近,我们对该样品池进行了开放式改装(尤其适用于超高磁场),并找到了其内部平均电势的解析解。特定 "正则化 "电极上的电压决定了电势与双曲电势的接近程度。在本文中,我们将通过分析找到这些 "正则化 "电极上的最佳电压。这将有助于阱制造后的进一步分析和调整。
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The analytical solution for the optimum voltage on regularizing electrodes of the open dynamically harmonized cell.

The Fourier transform ion cyclotron resonance method holds the lead in mass accuracy and resolving power among all other mass spectrometry methods. The dynamically harmonized cell is largely responsible for the supremacy. This cell has an ideal hyperbolic trapping potential after averaging over fast cyclotron motion. Recently we have introduced an open modification of the cell (especially useful with ultrahigh magnetic fields) and have found the analytical solution for the averaged potential inside it. The voltage on specific "regularizing" electrodes determines how close a potential is to the hyperbolic one. In this article, we find the optimal voltage on these "regularizing" electrodes analytically. This will assist with both further analysis and tuning of the trap after manufacturing.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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