Organo-cation catalyzed enantioselective α-hydroxylation of pyridinone-fused lactones: asymmetric synthesis of SN-38 and irinotecan?

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DOI:10.1039/d4cc03580a
作者：Jin-Rui Tian ,?Yu-Hao Qiao ,?Qing-Bo Zhuang ,?Rong Fan ,?Zhen Li ,?Xiao-Ming Zhang ,?Fu-Min Zhang ,?Yong-Qiang Tu
文献类型：期刊论文
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Royal Society of Chemistry (RSC)

Abstract：A catalytic asymmetric α-hydroxylation of pyridinone-fused lactones, containing the core structure of camptothecin, is described. Development of a novel spiropyrrolidine amide (SPA) derived

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