{"title":"Synthesis and x-ray crystal structure of chlorotriphenyl {cis-1,2-bis(diphenylphosphinyl)ethylene}tin(IV): A case of unidentate dioxo-diphosphine","authors":"Corrado Pelizzi, Giancarlo Pelizzi","doi":"10.1016/0020-1650(80)80026-2","DOIUrl":null,"url":null,"abstract":"<div><p>A 1:1 adduct between chlorotriphenyltin and <em>cis</em>-1,2-bis(diphenylphosphinyl)ethylene has been synthesized and characterized. The X-ray analysis has revealed a trigonal bipyramidal arrangement around tin involving three carbon atoms, the chloride ion and one of the two oxygen atoms from a unidentate phosphorus ligand.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1980-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(80)80026-2","citationCount":"18","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165080800262","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 18
Abstract
A 1:1 adduct between chlorotriphenyltin and cis-1,2-bis(diphenylphosphinyl)ethylene has been synthesized and characterized. The X-ray analysis has revealed a trigonal bipyramidal arrangement around tin involving three carbon atoms, the chloride ion and one of the two oxygen atoms from a unidentate phosphorus ligand.
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