Impact of aerosols on surface ozone during COVID-19 pandemic in southern India: A multi-instrumental approach from ground and satellite observations, and model simulations

Abstract

The World Health Organization (WHO) declared the coronavirus disease of 2019 (COVID-19) as a pandemic due to its widespread global infection. This has resulted in lockdown under different phases in many nations, including India, around the globe. In the present study, we report the impact of aerosols on surface ozone in the context of pre-lockdown (01^st - 24th March 2020 (PLD)), lockdown phase1 (25th March to 14th April 2020 (LDP1)), and lockdown phase 2 (15th April to 03^rd May 2020 (LDP2)) on clear days at a semi-arid site, Anantapur in southern India using both in situ observations and model simulations. Collocated measurements of surface ozone (O₃), aerosol optical depth (AOD), black carbon mass concentration (BC), total columnar ozone (TCO), solar radiation (SR), and ultraviolet radiation (UV-A) data were collected using an Ozone analyzer, MICROTOPS sunphotometer, Ozonometer, Aethalometer, and net radiometer during the study period. The diurnal variations of O₃ and BC exhibited an opposite trend during three phases. The concentrations of ozone were ~10.7% higher during LDP1 (44.8 ± 5.2 ppbv) than the PLD (40.5 ± 6.0 ppbv), which mainly due to an unprecedented reduction in NOx emissions leading to a lower O₃ titration by NO. The prominent increase in the surface zone during LDP1 is reasonably consistent with the observed photolysis frequencies (j (O¹D)) through Tropospheric Ultraviolet and Visible (TUV) model. The results show that a pronounced spectral and temporal variability in the AOD during three lockdown phases is mainly due to distinct aerosol sources. The increase in AOD during LDP2 due to long-range transport can bring large amounts of mineral dust and smoke aerosols from the west Asian region and central India, and which is reasonably consistent with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) air mass back trajectories and Moderate Resolution Imaging Spectroradiometer (MODIS) fire counts analysis over the measurement location. Overall, a drastic reduction in BC concentration (~8.4%) and AOD (10.8%) were observed in the semi-arid area during LDP1 with correspondence to PLD. The columnar aerosol size distributions retrieved from the spectral AODs followed power-law plus unimodal during three phases. The absorption angstrom exponent (AAE) analysis reveals a predominant contribution to the BC from biomass burning activities during the lockdown period over the measurement location.