Gasoline Production from Coconut Oil Using The Ni-MCM-41 and Co/Ni-MCM-41 Catalyst

Pub Date : 2017-04-30 DOI:10.20961/JKPK.V2I1.8516
Laila Badriyah, I. Falah
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引用次数: 1

Abstract

Gasoline have been produced from coconut oil using MCM-41, NiMCM-41, and Co/NiMCM-41 catalyst. The acidity of catalyst was analysed by Fourier Transformation Infra-Red Spectroscopy (FTIR). The yields of cracking product were analysed by Gas Chromatography-Mass Spectroscopy (GC-MS). The catalyst of Co/NiMCM-41 has the highest acidity than MCM-41 and NiMCM-41. It is caused by the effect of adding d orbital from Co and Ni. This cracking process is batch system, and the catalyst pellets were made at the temperature of 400 oC. The highest gasoline product was obtained using the Co/NiMCM-41 catalyst with 89.53 % w/w yield. The major liquid product from the cracking process using MCM-41, NiMCM-41, dan Co/NiMCM-41 catalysts were estimated as 1-octena, octane, nonane; 1-octene, 1-nonene, nonane; 1-octene, octane, nonane, respectively.
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Ni-MCM-41和Co/Ni-MCM-41催化剂催化椰油制汽油
采用MCM-41、NiMCM-41和Co/NiMCM-41催化剂从椰子油中制备汽油。用傅里叶变换红外光谱(FTIR)分析了催化剂的酸度。采用气相色谱-质谱联用技术对裂解产物收率进行了分析。Co/NiMCM-41催化剂的酸性高于MCM-41和NiMCM-41。这是由Co和Ni加入d轨道的影响引起的。该裂化工艺为间歇制,催化剂球团的制备温度为400℃。Co/NiMCM-41催化剂的汽油收率最高,w/w收率为89.53%。MCM-41、NiMCM-41和Co/NiMCM-41催化剂催化裂化的主要液体产物为1-辛烷、辛烷和壬烷;-辛烯,-壬烯,壬烷;1-辛烯,辛烷,壬烷。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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