David Trollet, Stéphane Roméro, Alain Mosset, Jean-Christian Trombe
{"title":"Synthèse et structure d’un oxalate de gadolinium ne contenant pas de molécule d’eau libre, [Gd(H2O)3]2(C2O4)3","authors":"David Trollet, Stéphane Roméro, Alain Mosset, Jean-Christian Trombe","doi":"10.1016/S1251-8069(99)80065-7","DOIUrl":null,"url":null,"abstract":"<div><p>A new family of lanthanide oxalate, [Ln(H<sub>2</sub>O)<sub>3</sub>]<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub> with Ln = Eu−Dy, has been characterized through the X-ray structural study of the gadolinium derivative. In contrast to the lanthanide oxalates already known, this structure is free of zeolitic water but it remains layered and the basic building blocks are preserved. The loss of zeolitic water leads to some deformations of the network units.</p></div>","PeriodicalId":100304,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy","volume":"325 11","pages":"Pages 663-670"},"PeriodicalIF":0.0000,"publicationDate":"1997-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1251-8069(99)80065-7","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1251806999800657","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
A new family of lanthanide oxalate, [Ln(H2O)3]2(C2O4)3 with Ln = Eu−Dy, has been characterized through the X-ray structural study of the gadolinium derivative. In contrast to the lanthanide oxalates already known, this structure is free of zeolitic water but it remains layered and the basic building blocks are preserved. The loss of zeolitic water leads to some deformations of the network units.