Energy and Deformation during Explosive Compaction of ZrB2-SiC Ultrahigh Temperature Ceramics

Jinping Li, S. Meng, Jiecai Han, Baolin Wang
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Abstract

To introduce a new technique and to choose the process parameters, ZrB2-SiC ultrahigh temperature ceramics (UHTCs) were prepared by mixing and explosive compaction. The explosive kinds or explosive mass was variable so as to change the explosive impact energy. We have studied the relationships of the explosive impact energy, the tube deformation energy, the powder compaction energy and the ratio of the explosive mass to the tube mass (R), the relationships of the tube deformation energy, the tube equivalent strain and the mass ratio R, and the relationships of the densities of the ZrB2 composites and the powder compact energy. The results show that the densities of the ZrB2 composites reach 93.37% of theory density. For any kind of explosive, the reduction of the outer diameter and the equivalent strain of the steel tubes raises gradually with the rise of the mass ratio R. Generally speaking, the higher the explosion speed of the explosive is, the larger the deformation degree and the equivalent strain of the steel tubes are. The explosive impact energy can be divided into two parts: the tube deformation energy and the powder compact energy; with the rise of the mass ratio R, the tube deformation energy hardly changes, while the explosive impact energy and powder compact energy increase synchronously, and the densities of the ZrB2 composites also increase gradually. The density of the ZrB2 composites produced by different explosives orders from big to small as RDX, Ammonium Nitrate, TNT, and Urea Nitrate.
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ZrB2-SiC超高温陶瓷爆炸压实过程中的能量与变形
采用混合-爆炸压实法制备了ZrB2-SiC超高温陶瓷(UHTCs),并对工艺参数进行了选择。改变炸药种类或炸药质量,从而改变爆炸冲击能。研究了爆炸冲击能、管变形能、粉末压实能与炸药质量比R的关系,管变形能、管等效应变与质量比R的关系,以及ZrB2复合材料密度与粉末压实能的关系。结果表明,ZrB2复合材料的密度达到理论密度的93.37%。对于任何一种炸药,钢管的外径减小量和等效应变随质量比r的增大而逐渐增大。一般来说,炸药的爆炸速度越快,钢管的变形程度和等效应变越大。爆炸冲击能可分为筒体变形能和粉末压实能两部分;随着质量比R的增大,管状变形能变化不大,而爆炸冲击能和粉末致密能同步增大,ZrB2复合材料的密度也逐渐增大。不同炸药制备的ZrB2复合材料的密度由大到小依次为RDX、硝酸铵、TNT、硝酸尿素。
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