Synthetic Elements

Eric R. Scerri
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Abstract

The periodic table consists of about 90 elements that occur naturally ending with element 92 uranium. This lack of precision is deliberate since one or two elements such as technetium were first created artificially and only later found to occur naturally on earth. This kind of occurrence provides a foreshadowing of things to come when we begin to discuss the transuranium elements, meaning those beyond uranium that have been artificially synthesized. Chemists and physicists have succeeded in synthesizing some of the elements that were missing between hydrogen (1) and uranium (92). In addition, they have synthesized a further 25, or so, new elements beyond uranium, although, again, one or two of these elements, like neptunium and plutonium, were later found to exist naturally in exceedingly small amounts. The existence of superheavy elements raises a number of interesting questions that pertain to the field of philosophy of science and also sociology of science. In fact, the very question of whether these superheavy elements actually exist needs to be dissected further, as it will be in the course of this chapter. The synthetic elements are extremely unstable, and only the lightest ones among them have been created in amounts large enough to be observed. Roughly speaking, the heavier the atom, the shorter its lifetime is. For example, the heaviest element for which there is now conclusive evidence is element 118, a few atoms of which have been created in just one single isotope form and with a half-life of less than a millisecond. Laypersons and specialists alike have asked themselves in what sense these elements can really be said to exist. The superheavy elements also have philosophical implications for the study of the periodic system as a whole and the question of whether there is a natural end to chemical periodicity. A related question, which has now become quite pressing, is the possible extension of the periodic table to include a new g-block which in formal terms should begin at element 121.
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人工合成成分
元素周期表由大约90种自然存在的元素组成,以92号元素铀结束。这种不精确是有意为之,因为像锝这样的一两种元素最初是人工制造出来的,后来才在地球上发现是自然存在的。这种情况为我们开始讨论超铀元素(即人工合成的铀以外的元素)时将要发生的事情埋下了伏笔。化学家和物理学家已经成功地合成了氢(1)和铀(92)之间缺失的一些元素。此外,他们还合成了铀以外的大约25种新元素,尽管其中有一两种元素,如镎和钚,后来被发现在自然界中以极少量的数量存在。超重元素的存在提出了许多有趣的问题,这些问题属于科学哲学和科学社会学领域。事实上,这些超重元素是否真的存在的问题需要进一步剖析,这将在本章中讨论。人工合成的元素极不稳定,其中只有最轻的元素被创造出来,其数量足以被观察到。粗略地说,原子越重,它的寿命越短。例如,目前有确凿证据的最重元素是118号元素,它的几个原子仅以一种同位素形式形成,半衰期不到一毫秒。外行人和专家都问过自己,在什么意义上说这些因素确实存在。超重元素还对整个周期系统的研究以及化学周期是否有自然结束的问题具有哲学意义。一个相关的问题,现在已经变得非常紧迫,是周期表的可能扩展,以包括一个新的g块,在形式上应该从第121号元素开始。
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BACK MATTER Group (n) and Group (n + 10) Relationships Isodiagonality Actinoid and Post-Actinoid Elements Lanthanoids, Group 3, and Their Connections
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