PENGARUH PENAMBAHAN LOGAM TRANSISI NIKEL TERHADAP SIFAT FISIS NANOROD ZnO

Sumarti Sumarti, Iwantono Iwantono, Awitdrus Awitdrus
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引用次数: 1

Abstract

Nickel-doped ZnO nanostructures have been successfully grown using seed mediated hydrothermal method. The growth of ZnO nanostructures has been done by concentration of the Ni-doped solution, is 8 mM with the growth temperature of  90°C in 7 hours. The grown ZnO nanostructures were characterized by using UV-Vis Spectroscopy, FESEM, and XRD. The UV-Vis spectra of the samples showed that the ZnO nanorod is hexagonal in shape with a strong absorption occured in the wavelength range of 300-380 nm. The FESEM images showed that geometrical shape of Ni-doped ZnO nanostructures are nanorod with a hexagonal and nanoflower faced shapes. XRD patterns observed show five diffraction peaks at 2θ: 32,09°; 34,76°; 36,65°; 47,95° and 56,97° for Ni doped ZnO nanostructures with crystal orientation of (100), (002), (101), (102) and (110) respectively. The strongest line was found in the crystal plane of (101).
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镍过渡金属对ZnO纳米纤维化性质的影响
采用种子介导水热法制备了镍掺杂ZnO纳米结构。在ni掺杂溶液浓度为8 mM、生长温度为90℃、生长时间为7小时的条件下,ZnO纳米结构得以生长。利用紫外可见光谱、FESEM和XRD对ZnO纳米结构进行了表征。紫外可见光谱分析表明,ZnO纳米棒呈六角形,在300 ~ 380 nm波长范围内发生强吸收。FESEM图像显示,ni掺杂ZnO纳米结构的几何形状为六边形纳米棒和纳米花面形状。XRD谱图显示在2θ: 32,09°处有5个衍射峰;34岁的76°;36, 65°;晶体取向分别为(100)、(002)、(101)、(102)和(110)的Ni掺杂ZnO纳米结构分别为47、95°和56、97°。最强谱线出现在(101)的晶面上。
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