Effects of PEO Additions on the Mechanical and Thermal Proprieties of PLA/PBAT Blends

Hyunho Jang, 연세대학교 패키징학과, S. Kwon, Yoojun Eom, Seungwoo Yoo, Su‐il Park
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Abstract

The blends of Poly(lactic acid) (PLA) and Poly(butylene adipate-co-terephthalate) (PBAT) have been recognized as a replacement for commodity plastic films and bags in biodegradable packaging industries. The purpose of this study is to identify changes in the thermal and mechanical properties of PLA/PBAT blends with the addition of poly(ethylene oxide)(PEO). PLA (80%) and PBAT (20%) were melt mixed with 0 to 10 phr of PEO and processed using a hot press. The addition of PEO into PLA/PBAT increased the elongation at break and improved thermal stability. With PEO addition, two melting temperature (Tm) peaks of PLA/PBAT merged into one peak showing improved miscibility. The result of this study showed that the addition of PEO increased the ductility and thermal stability of PLA/PBAT blends.
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PEO添加量对PLA/PBAT共混物力学和热性能的影响
聚乳酸(PLA)和聚己二酸丁烯-对苯二甲酸酯(PBAT)的共混物已被公认为是生物可降解包装工业中商品塑料薄膜和袋的替代品。本研究的目的是确定加入聚环氧乙烷(PEO)后PLA/PBAT共混物的热性能和机械性能的变化。将PLA(80%)和PBAT(20%)与0 ~ 10 phr的PEO熔体混合,使用热压机进行加工。PLA/PBAT中加入PEO提高了断裂伸长率,改善了热稳定性。添加PEO后,PLA/PBAT的两个熔融温度(Tm)峰合并为一个峰,表明混相性得到改善。研究结果表明,PEO的加入提高了PLA/PBAT共混物的延展性和热稳定性。
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