A Facile Synthesis of Copper Oxide Nanorods for Photocatalytic Degradation of Organic Pollutant and Inactivation of Pathogens

S. Botsa, D. Ramadevi, K. Basavaiah
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引用次数: 14

Abstract

In the recent years, green synthesis of nanomaterials has received a great attention to researchers in worldwide due to eco-friendly and scalable synthesis. Here, we report a green synthesis of copper oxide (CuO) nanorods via sonochemical assisted approach. The crystalline structure, band gap and morphology of as prepared CuO nanorods were investigated by UV-Vis diffuse reflectance (UV-Vis/DRS), Fourier Transform infrared spectroscopy, powder X-Ray diffraction (XRD) pattern and scanning electron microscopy (FESEM-EDX). The bandgap of as prepared CuO nanorods was found to be 2.0 eV, which is fall in the visible region of solar spectrum. FTIR demonstrated that there is strong interaction between Cu and oxygen in prepared CuO. XRD results reveal the formation of phase pure and crystalline CuO. FESEM images clearly show the rod like morphology of CuO and the presence of elemental copper and oxygen in EDX, confirms the formation of CuO. The photocatalytic degradation activity of CuO nanorods was examined against a model dye pollutant, nitrobenzene (NB) under visible light irradiation. CuO nanorods were effectively degraded the NB under visible light irradiation. CuO nanorods acts as potent and shows enhanced antimicrobial agent against pathogenic fungi, Candida albicans and bacteria, Escherichia coli.
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用于光催化降解有机污染物和致病菌的氧化铜纳米棒的简单合成
近年来,纳米材料的绿色合成因其具有环保性和可扩展性而受到国内外研究人员的广泛关注。在这里,我们报告了一个绿色合成氧化铜(CuO)纳米棒通过声化学辅助方法。采用紫外-可见漫反射(UV-Vis/DRS)、傅里叶变换红外光谱、粉末x射线衍射(XRD)和扫描电子显微镜(FESEM-EDX)对制备的CuO纳米棒的晶体结构、带隙和形貌进行了研究。所制备的氧化铜纳米棒的带隙为2.0 eV,落在太阳光谱可见区。红外光谱分析表明,在制备的CuO中,Cu与氧之间存在较强的相互作用。XRD结果表明,CuO形成了相纯的结晶。FESEM图像清晰地显示了CuO的棒状形态以及EDX中元素铜和氧的存在,证实了CuO的形成。研究了纳米棒在可见光照射下对模型染料污染物硝基苯(NB)的光催化降解活性。CuO纳米棒在可见光照射下能有效降解NB。氧化铜纳米棒对病原菌、白色念珠菌和细菌、大肠杆菌具有较强的抗菌作用。
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