Study on improving of interfacial microstructure and breakdown strength of polyethylene for power cables

Liangyu Gao, W. Guo, Huifeng Wang, Xiangxiao Qin, T. Mizutani
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Abstract

Special additives were used to modify the semiconducting layer chemically. In this paper, the relationship between the crystal orientation angle of the PE interface and the E/sub b/ has been deduced theoretically. The results of microstructure analysis showed that the modified semiconducting layer affected the crystal orientation angle of the PE interface, and revealed the formation of a very thin diffusion layer during the thermal process, and the suppression of the agglomeration of carbon particles in the semiconducting layer. The results of model cable specimens and treeing tests proved that additives AB/sub 2/ possessed the best modifying effect, in that they enhanced the breakdown strength E/sub b/ (1% Weibull distribution) of PE by 89% and the AC breakdown strength E/sub b/ by 40%, and could increased the treeing inception voltage of PE by 39%.<>
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改善电力电缆用聚乙烯界面微观结构和击穿强度的研究
采用特殊添加剂对半导体层进行化学改性。本文从理论上推导了PE界面晶体取向角与E/sub / b/之间的关系。微观结构分析结果表明,改性的半导体层影响了PE界面的晶体取向角,并在热过程中形成了极薄的扩散层,抑制了半导体层中碳颗粒的团聚。模型电缆试样和树形试验结果表明,添加剂AB/sub 2/的改性效果最好,可使PE的击穿强度E/sub b/(1%威布尔分布)提高89%,交流击穿强度E/sub b/提高40%,使PE的树形起始电压提高39%。
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