Nigora Kutlimurotova, Z. Smanova, Habibulla Tojimuhamedov, Z. Yaxshiyeva, Jasur Tursunqulov
{"title":"Extraction conductometric determination of scandium and thorium in kaolins","authors":"Nigora Kutlimurotova, Z. Smanova, Habibulla Tojimuhamedov, Z. Yaxshiyeva, Jasur Tursunqulov","doi":"10.56017/2181-1318.1035","DOIUrl":null,"url":null,"abstract":"A method for extraction conductometric determination of scandium and thorium with tributyl phosphate and trioctyl phosphine oxide in kaolin was developed. The equivalent electrical conductivity of the complex of scandium and thorium with 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid was found. A scheme for the separation and determination of kaolin content is proposed. The isotherms of scandium and thorium extraction are constructed. It was shown that at a concentration of nitric acid of 15.6 M they do not interfere with the determination of thorium and scandium.","PeriodicalId":127023,"journal":{"name":"Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.56017/2181-1318.1035","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
A method for extraction conductometric determination of scandium and thorium with tributyl phosphate and trioctyl phosphine oxide in kaolin was developed. The equivalent electrical conductivity of the complex of scandium and thorium with 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid was found. A scheme for the separation and determination of kaolin content is proposed. The isotherms of scandium and thorium extraction are constructed. It was shown that at a concentration of nitric acid of 15.6 M they do not interfere with the determination of thorium and scandium.
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