Adsorptive Potency of Activated Carbonized Avocado Pear Seeds (Persea Americana) and Activated Carbonized orange peels (Citrus Sinensis) in Eliminating Pb2+ ions in Contaminated Water.

O. Moses
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Abstract

Heavy metals persistence in water brings about undesirable effect on man and animal because they are not degradable like other organic pollutants. Carbonized Avocado Pear seed (CAPS) as well as carbonized orange peel (COP) was impregnated with Potassium hydroxide (KOH) in ratio 1:1 for 48 hours. The KOH impregnated CAPS and COP was separately washed and oven dried at 10 for 6 hours and thereafter heated in a muffle furnace (Carbolite AAF1100) at 2500C for 1 hour. The activated carbonized pear seed (ACAPS) and activated carbonized orange peel (ACOP) obtained was physicochemically described with SEM and FTIR. The adsorption route of Pb2+ ion on top of ACAPS as well as ACOP was examined by means of batch adsorption isotherm investigation. The Pb2+ ion adsorption pattern was assessed with Langmuir, DRK, Freundlich, Tempkin and Flory-Huggin isotherm models. The SEM photograph, disclosed that ACAPS posessed numerous openings of different dimensions whereas ACOP possessed less openings of lesser dimensions. R2 worth ranging from 0.92 to 1.00 was got, indicating that the whole isotherm models were capable of elucidating the connection in the figures got. The Pb2+ ion had a firmer attraction and adsorption capacity for ACAPS. On the overall, ACAPS was a superior adsorbent likened with ACOP for effectual elimination of Pb2+ ion owing to a blend of its numerous pores of different dimensions and it surface functional groups with a qm worth of 23.10 and 6.06mg/g in that order.
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活性炭牛油果梨籽和活性炭柑桔皮对污染水中Pb2+离子的吸附效果
重金属与其他有机污染物一样,具有不可降解性,在水中的持久性给人类和动物带来了不良影响。用氢氧化钾(KOH)以1:1的比例浸渍碳化牛油果梨籽(CAPS)和碳化橘皮(COP) 48小时。将KOH浸渍的CAPS和COP分别清洗并在10℃下烘干6小时,然后在马弗炉(Carbolite AAF1100)中在2500℃下加热1小时。用扫描电镜(SEM)和红外光谱(FTIR)对所制得的活性炭梨籽(ACAPS)和活性炭橘皮(ACOP)进行了理化表征。采用间歇吸附等温线研究了Pb2+离子在ACAPS和ACOP表面的吸附路线。采用Langmuir, DRK, Freundlich, Tempkin和Flory-Huggin等温模型对Pb2+离子的吸附模式进行了评价。扫描电镜照片显示,ACAPS具有许多不同尺寸的开口,而ACOP具有较少的小尺寸开口。得到的R2值在0.92 ~ 1.00之间,说明整个等温线模型能够阐明所得到的图中的联系。Pb2+离子对ACAPS具有较强的吸引力和吸附能力。综上所述,由于ACAPS具有大量不同尺寸的孔隙,其表面官能团的qm值依次为23.10和6.06mg/g,因此ACAPS在吸附Pb2+离子方面优于ACOP。
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