In Situ Trans-Esterification of Residual Oils in Spent Bleaching Clays from Vegetable Oil Refineries

Prapassorn Phakahan, K. Aryusuk, S. Lilitchan, K. Krisnangkura
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Abstract

Spent bleaching clays (SBCs) from vegetable oil refineries are industrial wastes. The clays contain large amount of oils (20-25%), which are good feedstock for biodiesels. Non-thermal in situ trans-methylation and trans-ethylation of oils in the SBC from rice bran oil (RBO), crude palm oil (CPO) and palm kernel oil (PKO) are rapid and can be accomplished in minutes with an alkaline catalyst. Thus, the process may possibly be used for large scale preparation of ethyl biodiesel.
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植物油精炼厂漂白废土残油原位反式酯化反应研究
植物油精炼厂的废漂白粘土(sbc)是工业废物。粘土中含有大量的油脂(20-25%),是生物柴油的良好原料。在SBC中,米糠油(RBO)、粗棕榈油(CPO)和棕榈仁油(PKO)的非热原位反式甲基化和反式乙基化反应迅速,在碱性催化剂下可在几分钟内完成。因此,该方法可能用于乙基生物柴油的大规模制备。
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