Production, Characterization, and Exergy Analysis of the Soybean Biodiesel Produced by Laboratory Scale

Rios Mas
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Abstract

The world's hegemonic energy model is mostly based on the burning of fossil fuels. The heavy reliance on oil, coal, and natural gas for power generation as well as the pollution resulting from burning such fuels is a growing global concern. Biodiesel from the transesterification of vegetable oils is a promising alternative source for diesel engines. The ANP, National Agency of Petroleum, Natural Gas and Biofuels, regulates fuels in Brazil. In this work, soybean biodiesel was produced on a laboratory scale through an alkaline transesterification reaction. An analysis of the exegetic efficiency of the process, the physical-chemical characterization of biodiesel, and a brief discussion on the following parameters were carried out: higher and lower calorific value, water content, specific mass at 20°C, kinematic viscosity at 40°C, acidity index and oxidative stability, verifying the adequacy to the parameters of ANP Resolutions nº 45/2014 and nº 798/2019. Considering the exergetic efficiency of 63.42% and the physical-chemical characterization, despite the non-conformities in water content and oxidative stability, soybean biodiesel proved to be a satisfactory alternative for renewable fuel.
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实验室规模生产大豆生物柴油的生产、表征和能量分析
世界霸权的能源模式主要建立在燃烧化石燃料的基础上。对石油、煤炭和天然气发电的严重依赖以及燃烧这些燃料造成的污染日益成为全球关注的问题。植物油酯交换制备的生物柴油是一种很有前途的柴油发动机替代燃料。ANP,即国家石油、天然气和生物燃料局,负责监管巴西的燃料。在本研究中,通过碱性酯交换反应在实验室规模上制备了大豆生物柴油。分析了该工艺的高效能、生物柴油的理化特性,并对以下参数进行了简要讨论:高热值和低热值、水分含量、20°C时的比质量、40°C时的运动粘度、酸度指数和氧化稳定性,验证了ANP决议nº45/2014和nº798/2019参数的充分性。考虑到63.42%的火用效率和理化性质,尽管大豆生物柴油在含水量和氧化稳定性方面存在差异,但证明大豆生物柴油是一种令人满意的可再生燃料替代品。
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