Mass spectrum analysis of a L.M.A.I.Ss using a novel software by MATLAB

T. Ganetsos, Nikolaos Laskaris, Ch. Lontos, B. Kotsos
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Abstract

In this work, mass spectrum analysis using a new novel software by MATLAB were tested in several liquid metal ion sources (LMAISs) such as AuGeSi, GaIN, ErFeCrNi, and AuGe. The relative intensities of the main ions of each source were determined. In AuGeSi source our results strongly point towards the co-existence of two mechanisms for the emission of doubly-charged monomer ions: direct field evaporation for the Ge/sup 2+/ and Si/sup 2+/ ions but Au/sup 2+/ is formed by the post-ionisation of Au/sup +/. In ErFeCrNi source according to Brandon's criterion Er/sup 2+/, Fe/sup 2+/ is likely to be field evaporated as doubly charged ions. Also, in AuSi alloy source Si/sup 2+/ is directly field-evaporated while Au/sup 2+/ must formed by the post-ionisation of Au/sup +/.
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利用MATLAB软件对l - m - a - is进行质谱分析
在这项工作中,使用MATLAB的新型软件在几种液态金属离子源(lmais)中进行了质谱分析,如AuGeSi, GaIN, ErFeCrNi和AuGe。测定了各源主离子的相对强度。在AuGeSi源中,我们的结果强烈地指向了两种双重带电单体离子发射机制的共存:Ge/sup 2+/和Si/sup 2+/离子的直接场蒸发,而Au/sup 2+/是由Au/sup +/的后电离形成的。在ErFeCrNi源中,根据Brandon准则Er/sup 2+/, Fe/sup 2+/很可能以双带电离子的形式被场蒸发。此外,在AuSi合金中,源Si/sup 2+/是直接场蒸发的,而Au/sup 2+/必须由Au/sup +/后电离形成。
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