The improvement of energy efficiency by generating hydroxyl radical on the surface of droplets for the water treatment using pulsed power discharge

Yoshihiro Sato, Keita Watanabe, Y. Minamitani
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Abstract

Pulsed power discharge in water is studied for advanced water treatment technology. The pulsed power generates streamer like discharge in water. The streamer discharge generates many active species (ozone, OH radical, ultraviolet rays etc.). All of them could be utilized to the decomposition of organic substances in water. However, to generate uniform streamer discharge is difficult in water because breakdown voltage in water is high. This phenomenon decreases efficiency of the water treatment. Therefore we are studying the water treatment method that contaminated water is sprayed as droplets from the top into the reactor that generates pulsed plasma in gaseous phase. The feature of our system is that contaminated water is sprayed as droplets from the top into the reactor that generates pulsed plasma in gaseous phase. Contaminated water reacts with active species in the streamer discharge directly. Hence this method has so much high efficiency for the water treatment. However, since OH radical that has short lifetime is generated near the streamer, some OH radicals would react before the reaction to the droplets. In this study, we designed a new reactor that the pulsed discharge occurs on the surface of the water droplets. By this design, it has been observed to improve the energy efficiency for water treatment. In other words, it is possible to decompose the organic substances in water with less energy and to come faster treatment.
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利用脉冲功率放电在水滴表面产生羟基自由基以提高能量效率
研究了水中脉冲功率放电的高级水处理技术。脉冲电源在水中产生流光状放电。流光放电产生许多活性物质(臭氧、OH自由基、紫外线等)。所有这些都可以用来分解水中的有机物。但由于水中击穿电压高,在水中很难产生均匀的流线型放电。这种现象降低了水处理的效率。因此,我们正在研究将污染的水以水滴的形式从顶部喷射到反应器中,从而产生气相脉冲等离子体的水处理方法。我们的系统的特点是污染的水以水滴的形式从顶部喷射到反应器中,从而产生气相的脉冲等离子体。受污染的水直接与流光排放中的活性物质发生反应。因此,该方法在水处理中具有很高的效率。然而,由于氢氧根的寿命较短,在飘带附近产生,一些氢氧根会先于液滴发生反应。在本研究中,我们设计了一种脉冲放电发生在水滴表面的新型反应器。通过这种设计,可以提高水处理的能源效率。换句话说,它可以用更少的能量分解水中的有机物质,并得到更快的处理。
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