J. Obi, Emmanuel Ifeanyi Victor, Azubuike Jeremiah Okolo, E. Onuh, C. C. Osuagwu, N. J. Okorocha, Olisa Nwuruku Alfred, J. O. Okechukwu
{"title":"Synthesis of Monoazo Dyes From Halogenated Arylamines and Fastness Properties on Cotton and Nylon","authors":"J. Obi, Emmanuel Ifeanyi Victor, Azubuike Jeremiah Okolo, E. Onuh, C. C. Osuagwu, N. J. Okorocha, Olisa Nwuruku Alfred, J. O. Okechukwu","doi":"10.54228/mjaret02220003","DOIUrl":null,"url":null,"abstract":"Some varieties of monoazo disperse dyes derived from halogenated arylamines were synthesized by simple diazotization and coupling to 1 and 2-naphthols. The impure dyes were recrystallized from ethanol solvent. Interestingly, all the dyes synthesized have colouristic properties. The purity and structural identities of the dyes obtained were confirmed by melting point, UV and IR spectrometry. The UV spectra of all the dyes synthesized revealed solvatochromism in solvent of different polarities and also halochromism. Fastness properties showed that all the dyes had better fastness properties on cotton than on nylon fabric, although deep dyeing was obtained on nylon fabric.","PeriodicalId":324503,"journal":{"name":"Multidisciplinary Journal for Applied Research in Engineering and Technology","volume":"5 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Multidisciplinary Journal for Applied Research in Engineering and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.54228/mjaret02220003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Some varieties of monoazo disperse dyes derived from halogenated arylamines were synthesized by simple diazotization and coupling to 1 and 2-naphthols. The impure dyes were recrystallized from ethanol solvent. Interestingly, all the dyes synthesized have colouristic properties. The purity and structural identities of the dyes obtained were confirmed by melting point, UV and IR spectrometry. The UV spectra of all the dyes synthesized revealed solvatochromism in solvent of different polarities and also halochromism. Fastness properties showed that all the dyes had better fastness properties on cotton than on nylon fabric, although deep dyeing was obtained on nylon fabric.
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