Development of Nanocrystalline Multi-Component (Ce,La,Y)-Fe-B Alloys Without Critical Rare Earth Elements for Cost-Effective Permanent Magnets

X. Liao, Jiasheng Zhang, Jiayi He, W. Fan, Hongya Yu, X. Zhong, Zhongwu Liu
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Abstract

Here we report the fully abundant rare earth-based nanocrystalline multi-component (Ce,La,Y)17Fe,sub>78B6 alloys containing no critical Nd/Pr/Dy/Tb with good combinations of room-temperature magnetic properties and thermal stability. The roles of La and Y substitutions for Ce have been fully understood. The enhanced coercivity Hcj by partial substitution of La is attributed to the increases of anisotropy field HA and the formation of continuously distributed grain boundaries resulting from the suppression of CeFe2 phase. Although Y substitution is not benefit for Hcj, the thermal stability has been effectively improved since Y2Fe14B shows weak temperature dependence of HA.
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不含关键稀土元素的纳米晶多组分(Ce,La,Y)-Fe-B永磁体合金的研制
本文报道了储量丰富的稀土基纳米晶多组分(Ce,La,Y)17Fe,sub>78B6合金,不含临界Nd/Pr/Dy/Tb,具有良好的室温磁性和热稳定性。La和Y取代Ce的作用已经得到了充分的认识。La的部分取代增强了矫顽力Hcj,这是由于各向异性场HA的增加和CeFe2相抑制导致的连续分布晶界的形成。虽然Y取代对Hcj没有好处,但由于Y2Fe14B对HA的温度依赖性较弱,因此有效地提高了热稳定性。
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